Doublet-emissive materials for organic light-emitting diodes: exciton formation and emission processes
S Gao, Z Cui, F Li - Chemical Society Reviews, 2023 - pubs.rsc.org
Doublet-emission is mainly discovered in stable radicals, lanthanide–metal complexes with
an f1 electron configuration and transition-metal complexes with a low-spin d5 electron …
an f1 electron configuration and transition-metal complexes with a low-spin d5 electron …
Attaching persistent organic free radicals to surfaces: how and why
The grounds in molecular materials lie on using functional molecules as building blocks that
self-assemble, following a bottom-up approach, into more complex structures that exhibit …
self-assemble, following a bottom-up approach, into more complex structures that exhibit …
Chiral-induced spin selectivity and non-equilibrium spin accumulation in molecules and interfaces: A first-principles study
Electrons moving through chiral molecules are selected according to their spin orientation
and the helicity of the molecule, an effect known as chiral-induced spin selectivity (CISS) …
and the helicity of the molecule, an effect known as chiral-induced spin selectivity (CISS) …
The first decade of organic spintronics research
The first decade of organic spintronics research has benefitted from the analogy and
previous experience of the inorganic spintronics field, coupled with the unlimited versatility …
previous experience of the inorganic spintronics field, coupled with the unlimited versatility …
Molecular and Spin Structures of a Through‐Space Conjugated Triradical System
T Kodama, M Aoba, Y Hirao, SM Rivero… - Angewandte …, 2022 - Wiley Online Library
A through‐space conjugated multi‐phenalenyl triradical 1 a has been prepared and
characterized. Partial occupancy of doubly degenerate molecular orbitals in 1 a leads to …
characterized. Partial occupancy of doubly degenerate molecular orbitals in 1 a leads to …
Non-Aufbau electronic structure in radical enzymes and control of the highly reactive intermediates
MH Khalilian, GA DiLabio - Chemical Science, 2024 - pubs.rsc.org
Radicals are highly reactive, short-lived chemical species that normally react
indiscriminately with biological materials, and yet, nature has evolved thousands of enzymes …
indiscriminately with biological materials, and yet, nature has evolved thousands of enzymes …
Anomalous effect of quantum interference in organic spin filters
The molecular topology in the single-molecule nanojunctions through which the de Broglie
wave propagates plays a crucial role in controlling the molecular conductance. The …
wave propagates plays a crucial role in controlling the molecular conductance. The …
Chemical Modulation of Charge Transport Perpendicular to the Molecular Plane
The electronic structure of molecules can have a considerable effect on charge transport
through molecular junctions. However, this is known only where molecular anchoring …
through molecular junctions. However, this is known only where molecular anchoring …
A high-spin organic diradical as a spin filter
Here, in this work we have designed a molecular bridge structure which can be used as a
spin filter where the prototypical highly ferromagnetic m-phenylene connected bis (aminoxyl) …
spin filter where the prototypical highly ferromagnetic m-phenylene connected bis (aminoxyl) …
Electronic communication as a transferable property of molecular bridges?
C Herrmann - The Journal of Physical Chemistry A, 2019 - ACS Publications
Electronic communication through molecular bridges is important for different types of
experiments, such as single-molecule conductance, electron transfer, superexchange spin …
experiments, such as single-molecule conductance, electron transfer, superexchange spin …