Noncovalent interactions in proteins and nucleic acids: Beyond hydrogen bonding and π-stacking
Understanding the noncovalent interactions (NCIs) among the residues of proteins and
nucleic acids, and between drugs and proteins/nucleic acids, etc., has extraordinary …
nucleic acids, and between drugs and proteins/nucleic acids, etc., has extraordinary …
Pnictogen bonding in coordination chemistry
The pnictogen bond (PnB) is a noncovalent attraction between electrophilic pnictogen
atoms, originated from the anisotropic distribution of electron density on Pn in a molecular …
atoms, originated from the anisotropic distribution of electron density on Pn in a molecular …
On the importance of σ–hole interactions in crystal structures
Elements from groups 14–18 and periods 3–6 commonly behave as Lewis acids, which are
involved in directional noncovalent interactions (NCI) with electron-rich species (lone pair …
involved in directional noncovalent interactions (NCI) with electron-rich species (lone pair …
Diaryliodoniums as hybrid hydrogen-and halogen-bond-donating organocatalysts for the Groebke–Blackburn–Bienaymé reaction
Dibenziodolium and diphenyliodonium triflates display high catalytic activity for the
multicomponent reaction that leads to a series of imidazopyridines. Density functional theory …
multicomponent reaction that leads to a series of imidazopyridines. Density functional theory …
Activation of a Metal‐Halogen Bond by Halogen Bonding
J Wolf, F Huber, N Erochok, F Heinen… - Angewandte Chemie …, 2020 - Wiley Online Library
In recent years, the non‐covalent interaction of halogen bonding (XB) has found increasing
application in organocatalysis. However, reports of the activation of metal‐ligand bonds by …
application in organocatalysis. However, reports of the activation of metal‐ligand bonds by …
Sulfonium and selenonium salts as noncovalent organocatalysts for the multicomponent Groebke–Blackburn–Bienaymé reaction
Sulfonium and selenonium salts, represented by S-aryl dibenzothiophenium and Se-aryl
dibenzoselenophenium triflates, were found to exhibit remarkable catalytic activity in the …
dibenzoselenophenium triflates, were found to exhibit remarkable catalytic activity in the …
On the importance of pnictogen and chalcogen bonding interactions in supramolecular catalysis
In this review, several examples of the application of pnictogen (Pn)(group 15) and
chalcogen (Ch) bonding (group 16) interactions in organocatalytic processes are gathered …
chalcogen (Ch) bonding (group 16) interactions in organocatalytic processes are gathered …
Iodonium salts as efficient iodine (III)-based noncovalent organocatalysts for Knorr-type reactions
Hypervalent iodine (III)-derivatives display higher catalytic activity than other aliphatic and
aromatic iodine (I)–or bromine (I)-containing substrates for a Knorr-type reaction of N-acetyl …
aromatic iodine (I)–or bromine (I)-containing substrates for a Knorr-type reaction of N-acetyl …
Supramolecular Assembly of Metal Complexes by (Aryl)I⋅⋅⋅d [PtII] Halogen Bonds
EA Katlenok, M Haukka, OV Levin… - … A European Journal, 2020 - Wiley Online Library
The theoretical data for the half‐lantern complexes [{Pt ()(μ‐)} 2][1–3; is cyclometalated 2‐Ph‐
benzothiazole; is 2‐SH‐pyridine (1), 2‐SH‐benzoxazole (2), 2‐SH‐tetrafluorobenzothiazole …
benzothiazole; is 2‐SH‐pyridine (1), 2‐SH‐benzoxazole (2), 2‐SH‐tetrafluorobenzothiazole …
Diaryliodonium Tetrachloroplatinates(II): Recognition of a Trifurcated Metal-Involving μ3-I···(Cl,Cl,Pt) Halogen Bond
Synthesis and X-ray characterization of the four diaryliodonium tetrachloroplatinates
(II)[Ar1Ar2I] 2 [PtCl4](Ar1/Ar2= Ph/Ph (1), 4-Cl-C6H4/2, 4, 6-(MeO) 3C6H2 (2), 4-Me-C6H4/2 …
(II)[Ar1Ar2I] 2 [PtCl4](Ar1/Ar2= Ph/Ph (1), 4-Cl-C6H4/2, 4, 6-(MeO) 3C6H2 (2), 4-Me-C6H4/2 …