Boron–nitrogen-doped π-conjugated systems have been regarded as a class of organic
materials with exceptional electronic and optical properties, which makes them promising in …

The intramolecular C–H borylation of (hetero) arenes and alkenes using electrophilic
boranes is a powerful transition metal free methodology for forming C–B bonds. These C–H …

Abstract Replacement of C C unit with its isoelectronic B N unit in aromatics provides a
new class of molecules with appealing properties, which have attracted great attention …

The substitution of isoelectronic B–N units for C–C units in aromatic hydrocarbons produces
novel heterocycles with structural similarities to the all-carbon frameworks, but with …

Despite the remarkable synthetic accomplishments in creating diverse polycyclic aromatic
hydrocarbons with B− N bonds (BN‐PAHs), their optoelectronic applications have been less …

It is very challenging to introduce azaborine into an electron-deficient arene system because
of unfavorable intramolecular electrophilic borylation reaction. In this report, we adopted a …

The previously elusive catalytic enantioselective construction of axially chiral B-aryl-1, 2-
azaborines with a C–B stereogenic axis has been realized through a chiral phosphoric acid …

The replacement of C= C units by their isoelectronic and isosteric B= N units (BN/CC
isosterism) in π‐conjugated organic compounds, as a strategy to produce novel organic …

In the periodic table of elements, boron (B, atomic number, 5) and nitrogen (N, atomic
number, 7) are neighboring to the carbon (C, atomic number, 6). Thus, the total electronic …

A tandem intramolecular electrophilic arene borylation reaction has been developed for the
synthesis of BN-fused polycyclic aromatic compounds such as 4b-aza-12b-boradibenzo [g …