Asymmetric hydrosilylation of prochiral alkenes followed by Tamao-Fleming oxidation is a
convenient method of synthesis of enantioenriched secondary alcohols. In this chapter …

Since the groundbreaking work by Gilman1 in the 1950s, cuprates have become versatile
tools in organic synthesis, more precisely, in 1, 4-addition reactions to R,-unsaturated …

The reduction of diverse functional groups is an essential protocol in organic chemistry.
Transition-metal catalysis has been successfully applied to the reduction of olefins, alkynes …

Examples of developments in asymmetric hydrogenation from various perspectives, in an
effort to improve efficiency, are reported. Discussed in this Account are (1) the improved …

The hydrosilylation of various ketones is mediated by an imidazolium salt/Cu (I) salt system
or by a well-defined (NHC) CuCl (NHC= N-heterocyclic carbene) catalyst precursor system …

Fluoride ion catalyzed multicomponent reactions for efficient synthesis of 4H-chromene and
N-arylquinoline derivatives in aqueous media - ScienceDirect Skip to main contentSkip to …

The value of a novel chemical transformation is often underappreciated at the time of its
discovery. The reasons are doubtlessly manifold, but the “chemical zeitgeist” subtly …

When complexed by selected ligands in either the BIPHEP or the SEGPHOS series, CuH is
an extremely reactive catalyst capable of effecting asymmetric hydrosilylations of aromatic …

This review article illustrates the concept and approach for designing new C2-symmetric
chelating atropisomeric chiral phosphines containing heterocyclic scaffolds. The versatility in …

Enantioselective copper (I) hydride (CuH)-catalyzed hydroamination has undergone
significant development over the past several years. To gain a general understanding of the …