Polyoxometalates (POMs) are discrete anionic metaloxygen clusters which can be regarded
as soluble oxide fragments. They exhibit a great diversity of sizes, nuclearities, and shapes …

This critical review presents a comprehensive study of transition-metal carboxylate clusters
which may serve as secondary building units (SBUs) towards construction and synthesis of …

With the rapid development of science and technology and the trend of multidisciplinary
pervasion, POM-based TM–RE heterometallic chemistry (POM= polyoxometalate, TM …

This critical review surveys the 3d substituted magnetic polyoxotungstate (POT) molecular
compounds reported these last ten years, illustrating the huge variety of topologies that …

The chemistry of large lanthanide clusters has long been a focus of coordination chemists
due to the unique properties conferred upon molecules that have f electrons. Recently, large …

A tubelike metal cluster containing 36 Gd and 12 Ni atoms was obtained by anion‐templated
self‐assembly of the metal ions (see picture for arrangement of the 48 metal ions in the …

The research on heterometallic 3d-4f polyoxometalates has made immense progress over
the last decade with a larger number of structures being reported every year until the present …

Rare earth carboxylates constitute an enormous group of compounds with various structures
and properties. The carboxylate group may be bonded to the metal cations in several ways …

Two rarely seen 2D coordination polymers based on huge 36-metal pure lanthanide
clusters,{[Gd36 (NA) 36 (OH) 49 (O) 6 (NO3) 6 (N3) 3 (H2O) 20] Cl2· 28H2O} n (1) and …

By control of mixed ligands with particular coordination sites, three novel three-dimensional
(3D) 4d− 4f heterometallic coordination polymers,[Ln4 (H2O) 2Ag (1, 3-bdc) 4 (inic) 5]⊙ n …