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Recent progress on NHC-stabilized early transition metal (group 3–7) complexes: Synthesis and applications
C Romain, S Bellemin-Laponnaz, S Dagorne - Coordination Chemistry …, 2020 - Elsevier
The present paper comprehensively reviews group 3–7 metal NHC complexes reported
since 2014, with emphasis on their current applications and fundamental reactivity. Thanks …
since 2014, with emphasis on their current applications and fundamental reactivity. Thanks …
Group 6 metal alkylidene and alkylidyne N-heterocyclic carbene complexes for olefin and alkyne metathesis
MJ Benedikter, F Ziegler, J Groos, PM Hauser… - Coordination Chemistry …, 2020 - Elsevier
The concept of metal imido and metal oxo alkylidene N-heterocyclic carbene (NHC)
catalysts for olefin metathesis is outlined. This includes the synthetic concepts for their …
catalysts for olefin metathesis is outlined. This includes the synthetic concepts for their …
Controlled cyclopolymerization of 1, 5-hexadiynes to give narrow band gap conjugated polyacetylenes containing highly strained cyclobutenes
For decades, cyclopolymerization of α, ω-diyne derivatives has been an effective method to
synthesize various soluble polyacetylenes containing five-to seven-membered rings in the …
synthesize various soluble polyacetylenes containing five-to seven-membered rings in the …
Stereoselective Ring‐Opening Metathesis Polymerization with Tungsten Sulfido Alkylidene N‐Heterocyclic Carbene Complexes
A series of cationic tungsten sulfido alkylidene N‐heterocyclic carbene (NHC) complexes
(W01–W09) of the general formula [W (S)(CHCMe3)(X)(NHC)(CMe3CN)+ B (ArF) 4−](NHC …
(W01–W09) of the general formula [W (S)(CHCMe3)(X)(NHC)(CMe3CN)+ B (ArF) 4−](NHC …
The Year of Polymers–100 Years of Macromolecular Chemistry.
But also, polymer-specific tasks and problems, such as micro-plastics and polymer-based
waste in general, will be a challenge in the second century of macromolecular science. A …
waste in general, will be a challenge in the second century of macromolecular science. A …
Reaction Mechanism of Ring-Closing Metathesis with a Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Catalyst
DFT calculations were carried out to explore all relevant pathways for the ring-closing
metathesis (RCM) reaction of a cationic molybdenum imido alkylidene N-heterocyclic …
metathesis (RCM) reaction of a cationic molybdenum imido alkylidene N-heterocyclic …