Multiphase chemistry under nanoconfinement: An electrochemical perspective

SM Lu, KJ Vannoy, JE Dick… - Journal of the American …, 2023 - ACS Publications
Most relevant systems of interest to modern chemists rarely consist of a single phase. Real-
world problems that require a rigorous understanding of chemical reactivity in multiple …

Electrochemistry under confinement

M Jaugstetter, N Blanc, M Kratz… - Chemical Society Reviews, 2022 - pubs.rsc.org
Although the term 'confinement'regularly appears in electrochemical literature, elevated by
continuous progression in the research of nanomaterials and nanostructures, up until today …

Interfacial solute flux promotes emulsification at the water| oil interface

GS Colón-Quintana, TB Clarke, JE Dick - Nature Communications, 2023 - nature.com
Emulsions are critical across a broad spectrum of industries. Unfortunately, emulsification
requires a significant driving force for droplet dispersion. Here, we demonstrate a …

Electrochemical quantification of accelerated FADGDH rates in aqueous nanodroplets

KJ Vannoy, I Lee, K Sode… - Proceedings of the …, 2021 - National Acad Sciences
Enzymes are molecules that catalyze reactions critical to life. These catalysts are often
studied in bulk water, where the influence of water volume on reactivity is neglected. Here …

Nanoscale electrochemistry in a copper/aqueous/oil three-phase system: surface structure–activity-corrosion potential relationships

E Daviddi, V Shkirskiy, PM Kirkman, MP Robin… - Chemical …, 2021 - pubs.rsc.org
Practically important metal electrodes are usually polycrystalline, comprising surface grains
of many different crystallographic orientations, as well as grain boundaries. In this study …

Screening the surface structure-dependent action of a benzotriazole derivative on copper electrochemistry in a triple-phase nanoscale environment

E Daviddi, V Shkirskiy, PM Kirkman… - The Journal of …, 2022 - ACS Publications
Copper (Cu) corrosion is a compelling problem in the automotive sector and in oil refinery
and transport, where it is mainly caused by the action of acidic aqueous droplets dispersed …

ACEstat: a diy guide to unlocking the potential of integrated circuit potentiostats for open-source electrochemical analysis

EW Brown, MW Glasscott, K Conley, J Barr… - Analytical …, 2022 - ACS Publications
Miniaturization of analytical instrumentation is paramount to enabling convenient in-field
sensing. The recent thrust in potentiostat miniaturization for electrochemical sensing and …

Selecting an optimal Faraday cage to minimize noise in electrochemical experiments

MW Glasscott, EW Brown, K Dorsey, CH Laber… - Analytical …, 2022 - ACS Publications
The ubiquitous Faraday cage, an experimental component particularly essential for
nanoelectrochemical measurements, is responsible for neutralizing noise introduced by …

Electrochemical-Shock Synthesis of Nanoparticles from Sub-femtoliter Nanodroplets

J Reyes-Morales, JE Dick - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Nanoparticles have witnessed immense development in the past several
decades due to their intriguing physicochemical properties. The modern chemist is …

In situ probing liquid/liquid interfacial kinetics through single nanodroplet electrochemistry

H Moon, JH Park - Analytical Chemistry, 2021 - ACS Publications
In this study, we report the new application of single nanodroplet electrochemistry to in situ
monitor the interfacial transfer kinetics of electroactive species across liquid/liquid interface …