Photocatalytic late-stage C–H functionalization
The emergence of modern photocatalysis, characterized by mildness and selectivity, has
significantly spurred innovative late-stage C–H functionalization approaches that make use …
significantly spurred innovative late-stage C–H functionalization approaches that make use …
Supramolecular coordination cages for artificial photosynthesis and synthetic photocatalysis
Because sunlight is the most abundant energy source on earth, it has huge potential for
practical applications ranging from sustainable energy supply to light driven chemistry. From …
practical applications ranging from sustainable energy supply to light driven chemistry. From …
Nitrogen-Centered Radicals in Functionalization of sp2 Systems: Generation, Reactivity, and Applications in Synthesis
C Pratley, S Fenner, JA Murphy - Chemical reviews, 2022 - ACS Publications
The chemistry of nitrogen-centered radicals (NCRs) has plentiful applications in organic
synthesis, and they continue to expand as our understanding of these reactive species …
synthesis, and they continue to expand as our understanding of these reactive species …
Enantioselective radical reactions using chiral catalysts
Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …
shown a continuous burst of new ideas and consequently a plethora of new catalytic …
Recent advances in the electrochemical generation of 1, 3-dicarbonyl radicals from C–H bonds
Q Wan, Z Zhang, ZW Hou, L Wang - Organic Chemistry Frontiers, 2023 - pubs.rsc.org
Electrochemistry, which employs electrons as reagents and avoids the use of traditional
redox reagents, becomes a powerful tool in oxidative dehydrogenation cross-coupling …
redox reagents, becomes a powerful tool in oxidative dehydrogenation cross-coupling …
Photocatalyzed [2σ+ 2σ] and [2σ+ 2π] Cycloadditions for the Synthesis of Bicyclo [3.1. 1] heptanes and 5-or 6-Membered Carbocycles
We report the use of photocatalysis for the homolytic ring-opening of carbonyl
cyclopropanes. In contrast to previous studies, our approach does not require a metal …
cyclopropanes. In contrast to previous studies, our approach does not require a metal …
Endogenous photosensitizers in human skin
Endogenous photosensitizers play a critical role in both beneficial and harmful light-induced
transformations in biological systems. Understanding their mode of action is essential for …
transformations in biological systems. Understanding their mode of action is essential for …
Aroyl fluorides as bifunctional reagents for dearomatizing fluoroaroylation of benzofurans
X Yu, QY Meng, CG Daniliuc… - Journal of the American …, 2022 - ACS Publications
The 2, 3-dihydrobenzofuran scaffold is widely found in natural products and biologically
active compounds. Herein, dearomatizing 2, 3-fluoroaroylation of benzofurans with aroyl …
active compounds. Herein, dearomatizing 2, 3-fluoroaroylation of benzofurans with aroyl …
Local reaction environment in electrocatalysis
Beyond conventional electrocatalyst engineering, recent studies have unveiled the
effectiveness of manipulating the local reaction environment in enhancing the performance …
effectiveness of manipulating the local reaction environment in enhancing the performance …
Resurgence and advancement of photochemical hydrogen atom transfer processes in selective alkane functionalizations
L Chang, S Wang, Q An, L Liu, H Wang, Y Li… - Chemical …, 2023 - pubs.rsc.org
The selective functionalization of alkanes has long been recognized as a prominent
challenge and an arduous task in organic synthesis. Hydrogen atom transfer (HAT) …
challenge and an arduous task in organic synthesis. Hydrogen atom transfer (HAT) …