Carbon–Carbon Bond Cleavage for Late-Stage Functionalization

YF Liang, M Bilal, LY Tang, TZ Wang, YQ Guan… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) introduces functional group or structural modification at
the final stage of the synthesis of natural products, drugs, and complex compounds. It is …

Mesoionic and related less heteroatom-stabilized N-heterocyclic carbene complexes: synthesis, catalysis, and other applications

A Vivancos, C Segarra, M Albrecht - Chemical reviews, 2018 - ACS Publications
Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …

Degradation of polyacrylates by one-pot sequential dehydrodecarboxylation and ozonolysis

AB Korpusik, A Adili, K Bhatt, JE Anatot… - Journal of the …, 2023 - ACS Publications
We establish a synthetically convenient method to degrade polyacrylate homopolymers.
Carboxylic acids are installed along the polymer backbone by partial hydrolysis of the ester …

Visible‐Light‐Promoted Switchable Selective Oxidations of Styrene Over Covalent Triazine Frameworks in Water

C Ayed, J Yin, K Landfester… - Angewandte Chemie …, 2023 - Wiley Online Library
Using photocatalytic oxidation to convert basic chemicals into high value compounds in
environmentally benign reaction media is a current focus in catalytic research. The …

[HTML][HTML] Synthesis of ruthenium complexes and their catalytic applications: A review

J Hafeez, M Bilal, N Rasool, U Hafeez… - Arabian Journal of …, 2022 - Elsevier
Ruthenium complexes are an important class that has multiple catalytic and biological
applications. Ruthenium has a remarkably broad and diversified chemical spectrum. In the …

Visible‐Light‐Induced Cycloaddition of α‐Ketoacylsilanes with Imines: Facile Access to β‐Lactams

JH Ye, P Bellotti, TO Paulisch… - Angewandte Chemie …, 2021 - Wiley Online Library
We report the synthesis of β‐lactams from α‐ketoacylsilanes and imines, which proceeds via
a formal [2+ 2] photochemical cycloaddition with in situ generation of siloxyketene. This mild …

Synthesis and Applications of Periodate for Fine Chemicals and Important Pharmaceuticals

S Arndt, PJ Kohlpaintner, K Donsbach… - … Process Research & …, 2022 - ACS Publications
An emerging interest for the application of periodate in the synthesis of active
pharmaceutical ingredients (APIs) and for the valorization of renewable feedstock is …

Double dehydrogenation of primary amines to nitriles by a ruthenium complex featuring pyrazole functionality

I Dutta, S Yadav, A Sarbajna, S De… - Journal of the …, 2018 - ACS Publications
A ruthenium (II) complex bearing a naphthyridine-functionalized pyrazole ligand catalyzes
oxidant-free and acceptorless selective double dehydrogenation of primary amines to …

Oxidative Cleavage of Alkenes by O2 with a Non-Heme Manganese Catalyst

Z Huang, R Guan, M Shanmugam… - Journal of the …, 2021 - ACS Publications
The oxidative cleavage of C═ C double bonds with molecular oxygen to produce carbonyl
compounds is an important transformation in chemical and pharmaceutical synthesis. In …

Selenium-catalyzed oxidation of alkenes: insight into the mechanisms and develo** trend

H Cao, R Qian, L Yu - Catalysis Science & Technology, 2020 - pubs.rsc.org
Oxidation of alkenes is a significant reaction in both academia and industry. In line with calls
for environmental protection and the concern of metal residues in products in the …