Carbon–Carbon Bond Cleavage for Late-Stage Functionalization
YF Liang, M Bilal, LY Tang, TZ Wang, YQ Guan… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) introduces functional group or structural modification at
the final stage of the synthesis of natural products, drugs, and complex compounds. It is …
the final stage of the synthesis of natural products, drugs, and complex compounds. It is …
Mesoionic and related less heteroatom-stabilized N-heterocyclic carbene complexes: synthesis, catalysis, and other applications
Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …
Degradation of polyacrylates by one-pot sequential dehydrodecarboxylation and ozonolysis
We establish a synthetically convenient method to degrade polyacrylate homopolymers.
Carboxylic acids are installed along the polymer backbone by partial hydrolysis of the ester …
Carboxylic acids are installed along the polymer backbone by partial hydrolysis of the ester …
Visible‐Light‐Promoted Switchable Selective Oxidations of Styrene Over Covalent Triazine Frameworks in Water
C Ayed, J Yin, K Landfester… - Angewandte Chemie …, 2023 - Wiley Online Library
Using photocatalytic oxidation to convert basic chemicals into high value compounds in
environmentally benign reaction media is a current focus in catalytic research. The …
environmentally benign reaction media is a current focus in catalytic research. The …
[HTML][HTML] Synthesis of ruthenium complexes and their catalytic applications: A review
Ruthenium complexes are an important class that has multiple catalytic and biological
applications. Ruthenium has a remarkably broad and diversified chemical spectrum. In the …
applications. Ruthenium has a remarkably broad and diversified chemical spectrum. In the …
Visible‐Light‐Induced Cycloaddition of α‐Ketoacylsilanes with Imines: Facile Access to β‐Lactams
JH Ye, P Bellotti, TO Paulisch… - Angewandte Chemie …, 2021 - Wiley Online Library
We report the synthesis of β‐lactams from α‐ketoacylsilanes and imines, which proceeds via
a formal [2+ 2] photochemical cycloaddition with in situ generation of siloxyketene. This mild …
a formal [2+ 2] photochemical cycloaddition with in situ generation of siloxyketene. This mild …
Synthesis and Applications of Periodate for Fine Chemicals and Important Pharmaceuticals
S Arndt, PJ Kohlpaintner, K Donsbach… - … Process Research & …, 2022 - ACS Publications
An emerging interest for the application of periodate in the synthesis of active
pharmaceutical ingredients (APIs) and for the valorization of renewable feedstock is …
pharmaceutical ingredients (APIs) and for the valorization of renewable feedstock is …
Double dehydrogenation of primary amines to nitriles by a ruthenium complex featuring pyrazole functionality
A ruthenium (II) complex bearing a naphthyridine-functionalized pyrazole ligand catalyzes
oxidant-free and acceptorless selective double dehydrogenation of primary amines to …
oxidant-free and acceptorless selective double dehydrogenation of primary amines to …
Oxidative Cleavage of Alkenes by O2 with a Non-Heme Manganese Catalyst
Z Huang, R Guan, M Shanmugam… - Journal of the …, 2021 - ACS Publications
The oxidative cleavage of C═ C double bonds with molecular oxygen to produce carbonyl
compounds is an important transformation in chemical and pharmaceutical synthesis. In …
compounds is an important transformation in chemical and pharmaceutical synthesis. In …
Selenium-catalyzed oxidation of alkenes: insight into the mechanisms and develo** trend
H Cao, R Qian, L Yu - Catalysis Science & Technology, 2020 - pubs.rsc.org
Oxidation of alkenes is a significant reaction in both academia and industry. In line with calls
for environmental protection and the concern of metal residues in products in the …
for environmental protection and the concern of metal residues in products in the …