Direct photocatalyzed hydrogen atom transfer (HAT) for aliphatic C–H bonds elaboration

L Capaldo, D Ravelli, M Fagnoni - Chemical Reviews, 2021 - ACS Publications
Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …

Photochemical and electrochemical applications of proton-coupled electron transfer in organic synthesis

PRD Murray, JH Cox, ND Chiappini, CB Roos… - Chemical …, 2021 - ACS Publications
We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

Radical C(sp3)–H functionalization and cross-coupling reactions

DL Golden, SE Suh, SS Stahl - Nature Reviews Chemistry, 2022 - nature.com
C–H functionalization reactions are playing an increasing role in the preparation and
modification of complex organic molecules, including pharmaceuticals, agrochemicals and …

Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C–H Functionalization

X Wang, J He, YN Wang, Z Zhao, K Jiang… - Chemical …, 2024 - ACS Publications
Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …

Catalyzing electrosynthesis: a homogeneous electrocatalytic approach to reaction discovery

JC Siu, N Fu, S Lin - Accounts of chemical research, 2020 - ACS Publications
Conspectus Electrochemistry has been used as a tool to drive chemical reactions for over
two centuries. With the help of an electrode and a power source, chemists are bestowed with …

Challenges and recent advancements in the transformation of CO 2 into carboxylic acids: straightforward assembly with homogeneous 3d metals

R Cauwenbergh, V Goyal, R Maiti, K Natte… - Chemical Society …, 2022 - pubs.rsc.org
The transformation of carbon dioxide (CO2) into useful chemicals, advanced materials, and
energy is a long-standing challenge in both fundamental science and industry. In recent …

Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts

S Rana, JP Biswas, S Paul, A Paik… - Chemical Society Reviews, 2021 - pubs.rsc.org
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Metal–organic frameworks as catalysts for organic synthesis: a critical perspective

V Pascanu, G González Miera, AK Inge… - Journal of the …, 2019 - ACS Publications
Recent advances in organic chemistry and materials chemistry have enabled the porosity of
new materials to be accurately controlled on the nanometer scale. In this context, metal …