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Recent advances in electrocatalysts, mechanism, and cell architecture for direct formic acid fuel cells
Direct formic acid fuel cells (DFAFCs) are potential candidates as power sources for various
applications, especially in portable electronics and medical diagnostic devices. Though they …
applications, especially in portable electronics and medical diagnostic devices. Though they …
General strategy for evaluating the d-band center shift and ethanol oxidation reaction pathway towards Pt-based electrocatalysts
JH Zheng, G Li, JM Zhang, N Cheng, LF Ji… - Science China …, 2023 - Springer
The catalytic performance of Pt-based catalysts depends sensitively on their d-band centers.
Nevertheless, there are still huge challenges to evaluate their d-band centers from …
Nevertheless, there are still huge challenges to evaluate their d-band centers from …
[HTML][HTML] Benchmarking catalysts for formic acid/formate electrooxidation
Energy production and consumption without the use of fossil fuels are amongst the biggest
challenges currently facing humankind and the scientific community. Huge efforts have been …
challenges currently facing humankind and the scientific community. Huge efforts have been …
Temperature-Dependent Kinetic Studies of the Chlorine Evolution Reaction over RuO2(110) Model Electrodes
Ultrathin single-crystalline RuO2 (110) films supported on Ru (0001) are employed as model
electrodes to extract kinetic information about the industrially important chlorine evolution …
electrodes to extract kinetic information about the industrially important chlorine evolution …
Formic acid oxidation on platinum electrodes: a detailed mechanism supported by experiments and calculations on well-defined surfaces
In spite of the fact that the formic acid oxidation reaction on electrode surfaces has been
extensively investigated, a detailed mechanism explaining all the available experimental …
extensively investigated, a detailed mechanism explaining all the available experimental …
Further insights into the formic acid oxidation mechanism on platinum: pH and anion adsorption effects
The influence of the electrolyte pH in the formic acid oxidation reaction on a polyoriented Pt
electrode in the presence of different anions, including sulfate, perchlorate, phosphate and …
electrode in the presence of different anions, including sulfate, perchlorate, phosphate and …
[HTML][HTML] The role of coordinating anions in the supporting electrolyte during the electrocatalytic oxidation of glycerol on Pt electrodes
This research explores the glycerol electrooxidation reaction (GEOR) on a platinum
electrode, with a special emphasis on the role of the chemical properties of the anion …
electrode, with a special emphasis on the role of the chemical properties of the anion …
Formic acid oxidation on platinum: a simple mechanistic study
The oxidation of small organic acids on noble metal surfaces under electrocatalytic
conditions is important for the operation of fuel cells and is of scientific interest, but the basic …
conditions is important for the operation of fuel cells and is of scientific interest, but the basic …
[HTML][HTML] Standard-state entropies and their impact on the potential-dependent apparent activation energy in electrocatalysis
The apparent activation energy, E app, is a common measure in thermal catalysis to discuss
the activity and limiting steps of catalytic processes on solid-state materials. Recently, the …
the activity and limiting steps of catalytic processes on solid-state materials. Recently, the …
Apparent activation energy in electrochemical multistep reactions: A description via sensitivities and degrees of rate control
Activation energy is a well-known empirical parameter in chemical kinetics that
characterizes the dependence of the chemical rate coefficients on the temperature and …
characterizes the dependence of the chemical rate coefficients on the temperature and …