Photoprotection: extending lessons learned from studying natural sunscreens to the design of artificial sunscreen constituents

LA Baker, B Marchetti, TNV Karsili… - Chemical Society …, 2017 - pubs.rsc.org
Evolution has ensured that plants and animals have developed effective protection
mechanisms against the potentially harmful effects of incident ultraviolet radiation (UVR) …

Gas-phase femtosecond particle spectroscopy: a bottom-up approach to nucleotide dynamics

VG Stavros, JRR Verlet - Annual Review of Physical Chemistry, 2016 - annualreviews.org
We summarize how gas-phase ultrafast charged-particle spectroscopy has been used to
provide an understanding of the photophysics of DNA building blocks. We focus on adenine …

Ultrafast photoprotecting sunscreens in natural plants

LA Baker, MD Horbury, SE Greenough… - The Journal of …, 2016 - ACS Publications
We explore the ultrafast photoprotective properties of a series of sinapic acid derivatives in a
range of solvents, utilizing femtosecond transient electronic absorption spectroscopy. We …

A perspective on the ultrafast photochemistry of solution-phase sunscreen molecules

LA Baker, SE Greenough… - The Journal of Physical …, 2016 - ACS Publications
Sunscreens are one of the most common ways of providing on-demand additional
photoprotection to the skin. Ultrafast transient absorption spectroscopy has recently proven …

Broadband ultrafast photoprotection by oxybenzone across the UVB and UVC spectral regions

LA Baker, MD Horbury, SE Greenough… - Photochemical & …, 2015 - Springer
Recent studies have shed light on the energy dissipation mechanism of oxybenzone, a
common ingredient in commercial sunscreens. After UVA photoexcitation, the dissipation …

Bottom-up excited state dynamics of two cinnamate-based sunscreen filter molecules

Y Peperstraete, M Staniforth, LA Baker… - Physical Chemistry …, 2016 - pubs.rsc.org
Methyl-E-4-methoxycinnamate (E-MMC) is a model chromophore of the commonly used
commercial sunscreen agent, 2-ethylhexyl-E-4-methoxycinnamate (E-EHMC). In an effort to …

Ultrafast Spectroelectrochemistry of the Catechol/o‐Quinone Redox Couple in Aqueous Buffer Solution

S Goia, GW Richings, MAP Turner… - …, 2024 - Wiley Online Library
Eumelanin is a natural pigment found in many organisms that provides photoprotection from
harmful UV radiation. As a redox‐active biopolymer, the structure of eumelanin is thought to …

Photodynamics of potent antioxidants: ferulic and caffeic acids

MD Horbury, LA Baker, WD Quan… - Physical Chemistry …, 2016 - pubs.rsc.org
The dynamics of ferulic acid (3-(4-hydroxy-3-methoxyphenyl)-2-propenoic acid) and caffeic
acid (3-(3, 4-dihydroxyphenyl)-2-propenoic acid) in acetonitrile, dioxane and water at pH 2.2 …

Observing and understanding the ultrafast photochemistry in small molecules: applications to sunscreens

LA Baker, VG Stavros - Science Progress, 2016 - journals.sagepub.com
In this review, we discuss the importance of biological and artificial photoprotection against
overexposure to harmful ultraviolet radiation. Transient electronic and transient vibrational …

Intermolecular hydrogen bonding modulates O‐H photodissociation in molecular aggregates of a catechol derivative

C Grieco, FR Kohl, Y Zhang, S Natarajan… - Photochemistry and …, 2019 - Wiley Online Library
The catechol functional group plays a major role in the chemistry of a wide variety of
molecules important in biology and technology. In eumelanin, intermolecular hydrogen …