Challenges and recent advancements in the transformation of CO 2 into carboxylic acids: straightforward assembly with homogeneous 3d metals

R Cauwenbergh, V Goyal, R Maiti, K Natte… - Chemical Society …, 2022 - pubs.rsc.org
The transformation of carbon dioxide (CO2) into useful chemicals, advanced materials, and
energy is a long-standing challenge in both fundamental science and industry. In recent …

Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts

MR Elsby, RT Baker - Chemical Society Reviews, 2020 - pubs.rsc.org
The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …

Reversible hydrogenation of carbon dioxide to formic acid using a Mn-pincer complex in the presence of lysine

D Wei, R Sang, P Sponholz, H Junge, M Beller - Nature Energy, 2022 - nature.com
Efficient hydrogen storage and release are essential for effective use of hydrogen as an
energy carrier. In principle, formic acid could be used as a convenient hydrogen storage …

Ligand-Bound CO2 as a Nonclassical Route toward Efficient Photocatalytic CO2 Reduction with a Ni N-Confused Porphyrin

H Yuan, A Krishna, Z Wei, Y Su, J Chen… - Journal of the …, 2024 - ACS Publications
Implementing the synergistic effects between the metal and the ligand has successfully
streamlined the energetics for CO2 activation and gained high catalytic activities …

[HTML][HTML] Synthesis of ruthenium complexes and their catalytic applications: A review

J Hafeez, M Bilal, N Rasool, U Hafeez… - Arabian Journal of …, 2022 - Elsevier
Ruthenium complexes are an important class that has multiple catalytic and biological
applications. Ruthenium has a remarkably broad and diversified chemical spectrum. In the …

Carbon dioxide hydrogenation to formate catalyzed by a bench-stable, non-pincer-type Mn (I) alkylcarbonyl complex

S Kostera, S Weber, M Peruzzini, LF Veiros… - …, 2021 - ACS Publications
The catalytic reduction of carbon dioxide is a process of growing interest for the use of this
simple and abundant molecule as a renewable building block in C1-chemical synthesis and …

Hydrogenation and Cross-Coupling Reactions Catalyzed by Mn, Fe, and Co Aromatic Pincer Complexes

L González-Sebastián, A Reyes-Sanchez… - …, 2023 - ACS Publications
Currently, the development of environmentally benign and effective catalytic reactions for
organic synthesis based on low-cost and abundant metals is one of the central research …

Sustainable catalysis with fluxional acridine-based PNP pincer complexes

S Kar, D Milstein - Chemical Communications, 2022 - pubs.rsc.org
Because of the widespread use of fossil fuels and the resulting global warming,
development of sustainable catalytic transformations is now more important than ever to …

The rise of manganese-catalyzed reduction reactions

P Schlichter, C Werlé - Synthesis, 2022 - thieme-connect.com
Recent developments in manganese-catalyzed reducing transformations—hydrosilylation,
hydroboration, hydrogenation, and transfer hydrogenation—are reviewed herein. Over the …

Manganese promoted (Bi) carbonate hydrogenation and formate dehydrogenation: Toward a circular carbon and hydrogen economy

D Wei, X Shi, P Sponholz, H Junge… - ACS Central Science, 2022 - ACS Publications
We report here a feasible hydrogen storage and release process by interconversion of
readily available (bi) carbonate and formate salts in the presence of naturally occurring α …