Asymmetric hydrogenation catalyzed by first-row transition metal complexes

J Wen, F Wang, X Zhang - Chemical Society Reviews, 2021 - pubs.rsc.org
This review provides a comprehensive view of the application of first-row transition metals in
asymmetric hydrogenation and asymmetric transfer hydrogenation. The catalytic behavior of …

Toward a mechanistic understanding of electrocatalytic nanocarbon

EJ Askins, MR Zoric, M Li, Z Luo, K Amine… - Nature …, 2021 - nature.com
Electrocatalytic nanocarbon (EN) is a class of material receiving intense interest as a
potential replacement for expensive, metal-based electrocatalysts for energy conversion and …

Triarylmethyl cation redox mediators enhance Li–O2 battery discharge capacities

EJ Askins, MR Zoric, M Li, R Amine, K Amine… - Nature Chemistry, 2023 - nature.com
A major impediment to Li–O2 battery commercialization is the low discharge capacities
resulting from electronically insulating Li2O2 film growth on carbon electrodes. Redox …

What distinguishes the strength and the effect of a Lewis acid: analysis of the Gutmann–Beckett method

P Erdmann, L Greb - Angewandte Chemie, 2022 - Wiley Online Library
IUPAC defines Lewis acidity as the thermodynamic tendency for Lewis pair formation. This
strength property was recently specified as global Lewis acidity (gLA), and is gauged for …

Unexpected Roles of Triethanolamine in the Photochemical Reduction of CO2 to Formate by Ruthenium Complexes

RN Sampaio, DC Grills, DE Polyansky… - Journal of the …, 2019 - ACS Publications
A series of 4, 4′-dimethyl-2, 2′-bipyridyl ruthenium complexes with carbonyl ligands were
prepared and studied using a combination of electrochemical and spectroscopic methods …

Photoredox catalysis on unactivated substrates with strongly reducing iridium photosensitizers

JH Shon, D Kim, MD Rathnayake, S Sittel… - Chemical …, 2021 - pubs.rsc.org
Photoredox catalysis has emerged as a powerful strategy in synthetic organic chemistry, but
substrates that are difficult to reduce either require complex reaction conditions or are not …

Exploiting the NADP+/NADPH-like Hydride-Transfer Redox Cycle with Bis-Imidazolium-Embedded Heterohelicene for Electrocatalytic Hydrogen Evolution Reaction

P Karak, SK Mandal, J Choudhury - Journal of the American …, 2023 - ACS Publications
Generation of clean energy in a viable manner demands efficient and sustainable catalysts.
One prospective method of clean energy generation is the electrochemical hydrogen …

Thermodynamic and Kinetic Activity Descriptors for the Catalytic Hydrogenation of Ketones

A Chirila, Y Hu, JC Linehan, DA Dixon… - Journal of the …, 2024 - ACS Publications
Activity descriptors are a powerful tool for the design of catalysts that can efficiently utilize H2
with minimal energy losses. In this study, we develop the use of hydricity and H–self …

Hydride Transfer-Based CO2 Reduction Catalysis: Navigating Metal Hydride to Organic Hydride in the Catalytic Loop

J Choudhury, R Bhardwaj… - Accounts of Chemical …, 2024 - ACS Publications
Conspectus The reductive conversion of carbon dioxide (CO2) into value-added products is
a process of immense importance. In the context of rising CO2 concentration in the …

Small organic molecule based on benzothiadiazole for electrocatalytic hydrogen production

M Axelsson, CFN Marchiori, P Huang… - Journal of the …, 2021 - ACS Publications
A small organic molecule 2, 1, 3-benzothiadiazole-4, 7-dicarbonitrile (BTDN) is assessed for
electrocatalytic hydrogen evolution on glassy carbon electrode and shows a hydrogen …