C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Abstract Manganese (I)‐catalyzed C− H alkynylations with organic halides occurred with
unparalleled substrate scope, and thus enabled step‐economical C− H functionalizations …

Non‐precious‐metal‐catalyzed reactions are of increasing importance in chemistry due to
the outstanding ecological and economic properties of these metals. In the subfield of metal …

Abstract Ruthenium (II)‐catalyzed meta‐selective C− H (di) fluoromethylation was
accomplished by phosphine and carboxylate cooperation. The remote C− H …

Use of a directing group in C–H functionalizations, often referred to as chelation assistance,
is one of the most reliable methods for achieving highly efficient and highly site-selective …

A versatile protocol for the C–H chalcogenation of indolines and indoles by means of copper
catalysis was established. The C–H functionalization occurred selectively at the C7 position …

Methods for positionally selective remote C− H functionalizations are in high demand.
Herein, we disclose the first heterogeneous ruthenium catalyst for meta‐selective C− H …

Nickel-catalyzed C–H activation has become a predominant and ubiquitous research area
in organic chemistry. Direct functionalization of inert C–H bonds to create functionally …

Highly enantioselective nickel‐catalyzed alkene endo‐hydroarylations were accomplished
with full selectivity by organometallic C− H activation. The asymmetric assembly of chiral six …