Adiabaticity of the Proton-Coupled Electron-Transfer Step in the Reduction of Superoxide Effected by Nickel-Containing Superoxide Dismutase Metallopeptide-Based …

J Shearer, JC Schmitt, HS Clewett - The Journal of Physical …, 2015‏ - ACS Publications
Nickel-containing superoxide dismutases (NiSODs) are bacterial metalloenzymes that
catalyze the disproportionation of O2–. These enzymes take advantage of a redox-active …