Synergistic dual transition metal catalysis
UB Kim, DJ Jung, HJ Jeon, K Rathwell… - Chemical Reviews, 2020 - ACS Publications
Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to
enable a reaction between two separately activated substrates, has unlocked a plethora of …
enable a reaction between two separately activated substrates, has unlocked a plethora of …
Gold-catalyzed reactions of specially activated alkynes, allenes, and alkenes
D Campeau, DF León Rayo, A Mansour… - Chemical …, 2020 - ACS Publications
This review describes the gold-catalyzed reactions of specially activated alkynes, allenes,
and alkenes. Such species are characterized by the presence of either electron-donating or …
and alkenes. Such species are characterized by the presence of either electron-donating or …
Synergistic catalysis: a powerful synthetic strategy for new reaction development
AE Allen, DWC MacMillan - Chemical science, 2012 - pubs.rsc.org
Synergistic catalysis is a synthetic strategy wherein both the nucleophile and the
electrophile are simultaneously activated by two separate and distinct catalysts to afford a …
electrophile are simultaneously activated by two separate and distinct catalysts to afford a …
Reactivity of gold complexes towards elementary organometallic reactions
M Joost, A Amgoune… - Angewandte Chemie …, 2015 - Wiley Online Library
For a while, the reactivity of gold complexes was largely dominated by their Lewis acid
behavior. In contrast to the other transition metals, the elementary steps of organometallic …
behavior. In contrast to the other transition metals, the elementary steps of organometallic …
When organocatalysis meets transition‐metal catalysis
C Zhong, X Shi - European Journal of Organic Chemistry, 2010 - Wiley Online Library
In the past several years, applications of transition metal complexes in tuning the reactivity of
organocatalyst‐promoted transformations have attracted increasing attention in the synthetic …
organocatalyst‐promoted transformations have attracted increasing attention in the synthetic …
Bimetallic Catalysis using Transition and Group 11 Metals: An Emerging Tool for C C Coupling and Other Reactions
Bimetallic catalysis refers to homogeneous processes in which either two transition metals
(TM), or one TM and one Group 11 (G11) element (occasionally Hg also), cooperate in a …
(TM), or one TM and one Group 11 (G11) element (occasionally Hg also), cooperate in a …
Gold‐Catalyzed Cross‐Couplings: New Opportunities for C C Bond Formation
Cross‐coupling is a powerful tool for the rapid construction of highly valuable compounds. In
this area of chemical transformations, new catalysts have recently emerged. Combining both …
this area of chemical transformations, new catalysts have recently emerged. Combining both …
Catalyzed catalysis using carbophilic Lewis acidic gold and Lewis basic palladium: synthesis of substituted butenolides and isocoumarins
Y Shi, KE Roth, SD Ramgren… - Journal of the American …, 2009 - ACS Publications
A new strategy for gold and palladium dual-catalytic reactivity and turnover, called catalyzed
catalysis, enhanced the synthetic usefulness of vinylgold intermediates by providing dual …
catalysis, enhanced the synthetic usefulness of vinylgold intermediates by providing dual …
Organogold reactivity with palladium, nickel, and rhodium: transmetalation, cross-coupling, and dual catalysis
JJ Hirner, Y Shi, SA Blum - Accounts of chemical research, 2011 - ACS Publications
Using two transition metals to simultaneously catalyze a reaction can offer distinct
opportunities for reactivity and selectivity when compared to using single-metal catalyst …
opportunities for reactivity and selectivity when compared to using single-metal catalyst …
Alkyne difunctionalization by dual gold/photoredox catalysis
A Tlahuext‐Aca, MN Hopkinson… - … A European Journal, 2016 - Wiley Online Library
Highly selective tandem nucleophilic addition/cross‐coupling reactions of alkynes have
been developed using visible‐light‐promoted dual gold/photoredox catalysis. The …
been developed using visible‐light‐promoted dual gold/photoredox catalysis. The …