Transition-state spectroscopy of partial wave resonances in the F+ HD reaction

W Dong, C **ao, T Wang, D Dai, X Yang, DH Zhang - Science, 2010 - science.org
Partial wave resonances, quasi-bound resonance states with well-defined rotation in the
transition state region of a chemical reaction, play a governing role in reaction dynamics but …

Extremely short-lived reaction resonances in Cl + HD (v = 1) → DCl + H due to chemical bond softening

T Yang, J Chen, L Huang, T Wang, C **ao, Z Sun… - Science, 2015 - science.org
The Cl+ H2 reaction is an important benchmark system in the study of chemical reaction
dynamics that has always appeared to proceed via a direct abstraction mechanism, with no …

Dynamical resonances in the fluorine atom reaction with the hydrogen molecule

X Yang, DH Zhang - Accounts of chemical research, 2008 - ACS Publications
The concept of transition state has played a crucial role in the field of chemical kinetics and
reaction dynamics. Resonances in the transition state region are important in many chemical …

Spiers Memorial Lecture: New directions in molecular scattering

GC Schatz, AM Wodtke, X Yang - Faraday Discussions, 2024 - pubs.rsc.org
The field of Molecular Scattering is reviewed as it pertains to gas-gas as well as gas-surface
chemical reaction dynamics. We emphasize the importance of collaboration of experiment …

Dielectric barrier discharge source for supersonic beams

K Luria, N Lavie, U Even - Review of scientific instruments, 2009 - pubs.aip.org
We present a new excitation source for pulsed supersonic beams. The excitation is based
on dielectric barrier discharge in the beam. It produces cold beams of metastable atoms …

Probing the resonance potential in the F atom reaction with hydrogen deuteride with spectroscopic accuracy

Z Ren, L Che, M Qiu, X Wang… - Proceedings of the …, 2008 - National Acad Sciences
Reaction resonances are transiently trapped quantum states along the reaction coordinate
in the transition state region of a chemical reaction that could have profound effects on the …

HF(v′ = 3) forward scattering in the F + H2 reaction: Shape resonance and slow-down mechanism

X Wang, W Dong, M Qiu, Z Ren… - Proceedings of the …, 2008 - National Acad Sciences
Crossed molecular beam experiments and accurate quantum dynamics calculations have
been carried out to address the long standing and intriguing issue of the forward scattering …

How Is C–H Vibrational Energy Redistributed in F + CHD31 = 1) → HF + CD3?

J Yang, D Zhang, B Jiang, D Dai, G Wu… - The Journal of …, 2014 - ACS Publications
The effects of CH stretching excitation on the F+ CHD3→ HF+ CD3 reaction are studied
experimentally using crossed-beam and time-sliced velocity map imaging techniques at the …

A new crossed molecular beam apparatus using time-sliced ion velocity imaging technique

G Wu, W Zhang, H Pan, Q Shuai, B Jiang… - Review of Scientific …, 2008 - pubs.aip.org
A new crossed molecular beam apparatus has been constructed for investigating polyatomic
chemical reactions using the time-sliced ion velocity map imaging technique. A unique …

Development of a stable source of atomic oxygen with a pulsed high-voltage discharge and its application to crossed-beam reactions

I Lu, WJ Huang, C Chaudhuri, WK Chen… - Review of Scientific …, 2007 - pubs.aip.org
To investigate the reactions of oxygen atoms with ethene and silane in a crossed-beam
condition, we developed a stable, highly intense, and short-pulsed source of atomic oxygen …