Engineering heterogeneous catalysis with strong metal–support interactions: characterization, theory and manipulation

T Pu, W Zhang, M Zhu - Angewandte Chemie International …, 2023 - Wiley Online Library
Strong metal–support interactions (SMSI) represent a classic yet fast‐growing area in
catalysis research. The SMSI phenomenon results in the encapsulation and stabilization of …

Renaissance of strong metal–support interactions

M Xu, M Peng, H Tang, W Zhou, B Qiao… - Journal of the American …, 2024 - ACS Publications
Strong metal–support interactions (SMSIs) have emerged as a significant and cutting-edge
area of research in heterogeneous catalysis. They play crucial roles in modifying the …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

Overturning CO2 Hydrogenation Selectivity with High Activity via Reaction-Induced Strong Metal–Support Interactions

H **n, L Lin, R Li, D Li, T Song, R Mu… - Journal of the …, 2022 - ACS Publications
Encapsulation of metal nanoparticles by support-derived materials known as the classical
strong metal–support interaction (SMSI) often happens upon thermal treatment of supported …

Efficient overall water splitting of a suspended photocatalyst boosted by metal-support interaction

Y Qi, B Zhang, G Zhang, Z Zheng, T **e, S Chen, G Ma… - Joule, 2024 - cell.com
Strong metal-support interaction (SMSI) has been widely discussed for activity promotion of
heterogeneous catalysis, but the effect of SMSI on photocatalysis remains unclear. Here, we …

Interfacial compatibility critically controls Ru/TiO2 metal-support interaction modes in CO2 hydrogenation

J Zhou, Z Gao, G **ang, T Zhai, Z Liu, W Zhao… - Nature …, 2022 - nature.com
Supports can widely affect or even dominate the catalytic activity, selectivity, and stability of
metal nanoparticles through various metal-support interactions (MSIs). However, underlying …

Propane dehydrogenation: catalyst development, new chemistry, and emerging technologies

S Chen, X Chang, G Sun, T Zhang, Y Xu… - Chemical SOCIETY …, 2021 - pubs.rsc.org
Propylene is an important building block for enormous petrochemicals including
polypropylene, propylene oxide, acrylonitrile and so forth. Propane dehydrogenation (PDH) …

A single site ruthenium catalyst for robust soot oxidation without platinum or palladium

Y Li, T Qin, Y Wei, J **ong, P Zhang, K Lai… - Nature …, 2023 - nature.com
The quest for efficient non-Pt/Pd catalysts has proved to be a formidable challenge for auto-
exhaust purification. Herein, we present an approach to construct a robust catalyst by …

Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity

TW Van Deelen, C Hernández Mejía, KP de Jong - Nature Catalysis, 2019 - nature.com
Metal nanoparticles stabilized on a support material catalyse many major industrial
reactions. Metal-support interactions in these nanomaterials can have a substantial …

Solid-state reaction synthesis of nanoscale materials: strategies and applications

A Kumar, S Dutta, S Kim, T Kwon, SS Patil… - Chemical …, 2022 - ACS Publications
Nanomaterials (NMs) with unique structures and compositions can give rise to exotic
physicochemical properties and applications. Despite the advancement in solution-based …