[HTML][HTML] Astrochemically relevant radicals and radical–molecule complexes: A new insight from matrix isolation

VI Feldman - International Journal of Molecular Sciences, 2023 - mdpi.com
The reactive open-shell species play a very important role in the radiation-induced
molecular evolution occurring in the cold areas of space and presumably leading to the …

Role of acetylene in the chemical evolution of carbon complexity

EO Pentsak, MS Murga… - ACS Earth and Space …, 2024 - ACS Publications
Acetylene, among the multitude of organic molecules discovered in space, plays a distinct
role in the genesis of organic matter. Characterized by its unique balance of stability and …

Non-energetic Formation of Ethanol via CCH Reaction with Interstellar H2O Ices. A Computational Chemistry Study

J Perrero, J Enrique-Romero… - ACS Earth and Space …, 2022 - ACS Publications
Ethanol (CH3CH2OH) is a relatively common molecule, often found in star-forming regions.
Recent studies suggest that it could be a parent molecule of several so-called interstellar …

Formation of complex organic molecules in molecular clouds: acetaldehyde, vinyl alcohol, ketene, and ethanol via the “energetic” processing of C2H2 ice

KJ Chuang, G Fedoseev, C Scirè, GA Baratta… - Astronomy & …, 2021 - aanda.org
Context. The simultaneous detection of organic molecules of the form C 2 H n O, such as
ketene (CH 2 CO), acetaldehyde (CH 3 CHO), and ethanol (CH 3 CH 2 OH), toward early …

An experimental and theoretical investigation into the formation of ketene (H2CCO) and ethynol (HCCOH) in interstellar analog ices

AM Turner, AS Koutsogiannis… - The Astrophysical …, 2020 - iopscience.iop.org
The formation of isomers of C 2 H 2 O—ketene (H 2 CCO), ethynol (HCCOH), and oxirene (c-
CHCHO)—was investigated in interstellar ice analogs composed of carbon monoxide and …

Formation and Evolution of H2C3O+• Radical Cations: A Computational and Matrix Isolation Study

PV Zasimov, DA Tyurin, SV Ryazantsev… - Journal of the …, 2022 - ACS Publications
The family of isomeric H2C3O+• radical cations is of great interest for physical organic
chemistry and chemistry occurring in extraterrestrial media. In this work, we have …

Matrix isolation in laboratory astrochemistry: state-of-the-art, implications and perspective

VI Feldman, SV Ryazantsev… - Russian Chemical …, 2021 - iopscience.iop.org
Recent progress in observational astronomy and astrophysics has stimulated intensive
laboratory studies aimed at elucidating the mechanisms of evolution of molecular matter in …

Radiation-induced transformations of matrix-isolated ethanol molecules at cryogenic temperatures: an FTIR study

PV Zasimov, EV Sanochkina, DA Tyurin… - Physical Chemistry …, 2023 - pubs.rsc.org
Ethanol (C2H5OH) is one of the most common alcohol molecules observed in various space
media (molecular clouds, star formation regions, and, highly likely, interstellar ices), where it …

Direct evidence for a radiation-induced synthesis of acetonitrile and isoacetonitrile from a 1: 1 CH 4⋯ HCN complex at cryogenic temperatures: is it a missing link …

AD Volosatova, MA Lukianova, PV Zasimov… - Physical Chemistry …, 2021 - pubs.rsc.org
Nitriles are important constituents of extraterrestrial media. Nitriles are supposed to play a
crucial role in prebiotic chemistry occurring in the interstellar medium. In this work, we have …

Quantitative assessment of the absorbed dose in cryodeposited noble-gas films under X-ray irradiation: Simulation vs. experiment

PV Zasimov, AV Belousov, IA Baranova… - Radiation Physics and …, 2020 - Elsevier
This work was aimed at quantitative determination of the absorbed doses under X-ray
irradiation of cryogenic deposited films, particularly related to the matrix isolation …