Toward a new era of SERS and TERS at the nanometer scale: From fundamentals to innovative applications

T Itoh, M Procházka, ZC Dong, W Ji… - Chemical …, 2023 - ACS Publications
Surface-enhanced Raman scattering (SERS) and tip-enhanced Raman scattering (TERS)
have opened a variety of exciting research fields. However, although a vast number of …

The rise and current status of polaritonic photochemistry and photophysics

R Bhuyan, J Mony, O Kotov, GW Castellanos… - Chemical …, 2023 - ACS Publications
The interaction between molecular electronic transitions and electromagnetic fields can be
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …

Understanding polaritonic chemistry from ab initio quantum electrodynamics

M Ruggenthaler, D Sidler, A Rubio - Chemical Reviews, 2023 - ACS Publications
In this review, we present the theoretical foundations and first-principles frameworks to
describe quantum matter within quantum electrodynamics (QED) in the low-energy regime …

Molecular chemistry in cavity strong coupling

K Hirai, JA Hutchison, H Uji-i - Chemical Reviews, 2023 - ACS Publications
The coherent exchange of energy between materials and optical fields leads to strong light–
matter interactions and so-called polaritonic states with intriguing properties, halfway …

Recent advances in triplet–triplet annihilation upconversion and singlet fission, towards solar energy applications

AJ Carrod, V Gray, K Börjesson - Energy & Environmental Science, 2022 - pubs.rsc.org
Solar energy is an ample renewable energy resource, with photovoltaic (PV) technology
enabling a direct route from light to electricity. Currently, PVs are limited in photon …

Optical metasurfaces for energy conversion

E Cortés, FJ Wendisch, L Sortino, A Mancini… - Chemical …, 2022 - ACS Publications
Nanostructured surfaces with designed optical functionalities, such as metasurfaces, allow
efficient harvesting of light at the nanoscale, enhancing light–matter interactions for a wide …

Light–matter interactions in hybrid material metasurfaces

J Guan, JE Park, S Deng, MJH Tan, J Hu… - Chemical …, 2022 - ACS Publications
This Review focuses on the integration of plasmonic and dielectric metasurfaces with
emissive or stimuli-responsive materials for manipulating light–matter interactions at the …

Vibration-cavity polariton chemistry and dynamics

AD Dunkelberger, BS Simpkins… - Annual review of …, 2022 - annualreviews.org
Molecular polaritons result from light-matter coupling between optical resonances and
molecular electronic or vibrational transitions. When the coupling is strong enough, new …

Theoretical challenges in polaritonic chemistry

J Fregoni, FJ Garcia-Vidal, J Feist - ACS photonics, 2022 - ACS Publications
Polaritonic chemistry exploits strong light–matter coupling between molecules and confined
electromagnetic field modes to enable new chemical reactivities. In systems displaying this …

Multi-scale molecular dynamics simulations of enhanced energy transfer in organic molecules under strong coupling

I Sokolovskii, RH Tichauer, D Morozov, J Feist… - Nature …, 2023 - nature.com
Exciton transport can be enhanced in the strong coupling regime where excitons hybridize
with confined light modes to form polaritons. Because polaritons have group velocity, their …