Nanoparticle-hydrogel composites: from molecular interactions to macroscopic behavior

C Dannert, BT Stokke, RS Dias - Polymers, 2019 - mdpi.com
Hydrogels are materials used in a variety of applications, ranging from tissue engineering to
drug delivery. The incorporation of nanoparticles to yield composite hydrogels has gained …

A (macro) molecular-level understanding of polymer network topology

Y Gu, J Zhao, JA Johnson - Trends in Chemistry, 2019 - cell.com
Topology plays a critical role in dictating the properties of many materials. In recent years,
with advances in synthetic and characterization techniques, substantial efforts have been …

Spatial inhomogeneity and dynamic fluctuations of polymer gels

M Shibayama - Macromolecular Chemistry and Physics, 1998 - Wiley Online Library
Polymer gels have two types of concentration fluctuations; liquidlike and solidlike
fluctuations. The former are time‐dependent (thermal) fluctuations and the latter are time …

Small angle neutron scattering study on poly (N‐isopropyl acrylamide) gels near their volume‐phase transition temperature

M Shibayama, T Tanaka, CC Han - The Journal of chemical physics, 1992 - pubs.aip.org
The small angle neutron scattering experiments were conducted on N‐isopropyl acrylamide
(NIPA) gels in D2O and on the corresponding NIPA solutions. The NIPA gels underwent a …

Nanostructural heterogeneity in polymer networks and gels

F Di Lorenzo, S Seiffert - Polymer Chemistry, 2015 - pubs.rsc.org
Many polymer networks and gels display nanostructural heterogeneity in the form of
spatially inhomogeneous crosslinking densities, along with additional topological defects …

Polyacrylamide− clay nanocomposite hydrogels: rheological and light scattering characterization

O Okay, W Oppermann - Macromolecules, 2007 - ACS Publications
The free-radical polymerization of acrylamide in aqueous clay dispersions and the structure
of the resulting polymer− clay nanocomposite hydrogels have been investigated by …

Origin of nanostructural inhomogeneity in polymer-network gels

S Seiffert - Polymer Chemistry, 2017 - pubs.rsc.org
Polymer-network gels often display nano-to microstructural spatial inhomogeneity of their
polymer-segmental and crosslinking densities, especially if they are formed by uncontrolled …

Structure characterization of tetra-PEG gel by small-angle neutron scattering

T Matsunaga, T Sakai, Y Akagi, U Chung… - …, 2009 - ACS Publications
The structure of Tetra-PEG gel, a new class of biocompatible, easy-made, and high-strength
hydrogel consisting of a four-arm polyethylene glycol (PEG) network, has been investigated …

SANS and SLS studies on tetra-arm PEG gels in as-prepared and swollen states

T Matsunaga, T Sakai, Y Akagi, U Chung… - …, 2009 - ACS Publications
A series of model networks consisting of polyethylene glycol (PEG), tetra-PEG gels, have
been prepared and their structure and dynamics have been investigated by small-angle …

Cystic fibrosis sputum: a barrier to the transport of nanospheres

NN Sanders, SC De Smedt… - American journal of …, 2000 - atsjournals.org
Cystic fibrosis (CF) is characterized by the presence of a viscoelastic mucus layer in the
upper airways and bronchi. The underlying problem is a mutation in the gene encoding the …