Decaborane: From Alfred Stock and rocket fuel projects to nowadays
IB Sivaev - Molecules, 2023 - mdpi.com
The review covers more than a century of decaborane chemistry from the first synthesis by
Alfred Stock to the present day. The main attention is paid to the reactions of the substitution …
Alfred Stock to the present day. The main attention is paid to the reactions of the substitution …
Macropolyhedral syn-B18H22, the “Forgotten” Isomer
The chemistry and physics of macropolyhedral B18H22 clusters have attracted significant
attention due to the interesting photophysical properties of anti-B18H22 (blue emission …
attention due to the interesting photophysical properties of anti-B18H22 (blue emission …
Handbook of Aggregation-Induced Emission, Volume 1: Tutorial Lectures and Mechanism Studies
Der erste Band des ultimativen Referenzwerks zur Wissenschaft und Anwendung
aggregationsinduzierter Emissionen Im Handbook of Aggregation-Induced Emission …
aggregationsinduzierter Emissionen Im Handbook of Aggregation-Induced Emission …
Inverted energy gap law for the nonradiative decay in fluorescent floppy molecules: larger fluorescence quantum yields for smaller energy gaps
A data survey on experimental fluorescence quantum yields of (multi) substituted dicyano-
distyrylbenzenes in fluid solution evidences that non-radiative decay increases with the …
distyrylbenzenes in fluid solution evidences that non-radiative decay increases with the …
Expanding Luminescence Horizons in Macropolyhedral Heteroboranes
J Bould, M Ehn, O Tok, D Bavol… - Angewandte …, 2024 - Wiley Online Library
Luminescence is observed in three novel macropolyhedral nineteen‐and eighteen‐vertex
chalcogenaboranes: Se2B17H17 (1), SeB17H19 (3) and SeB18H20 (4). This led us to the …
chalcogenaboranes: Se2B17H17 (1), SeB17H19 (3) and SeB18H20 (4). This led us to the …
Unveiling the role of upper excited electronic states in the photochemistry and laser performance of anti-B 18 H 22
In the search for innovative new light sources, the discovery that solutions of the boron
hydride anti-B18H22 generate photostable blue laser emission stands out in its significance …
hydride anti-B18H22 generate photostable blue laser emission stands out in its significance …
Metal-Catalyzed and Metal-Free Nucleophilic Substitution of 7-IB18H21
KP Anderson, PI Djurovich, VP Rubio, A Liang… - Inorganic …, 2022 - ACS Publications
In this work, two pathways of reactivity are investigated to generate site-specific substitutions
at the B7 vertex of the luminescent boron cluster, anti-B18H22. First, a palladium-catalyzed …
at the B7 vertex of the luminescent boron cluster, anti-B18H22. First, a palladium-catalyzed …
Effect of Iodination on the Photophysics of the Laser Borane anti-B18H22: Generation of Efficient Photosensitizers of Oxygen
Treatment of the laser borane anti-B18H22 (compound 1) with iodine in ethanol gives the
monoiodinated derivative 7-I-anti-B18H21 (compound 2) in 67% yield, or, by reaction with …
monoiodinated derivative 7-I-anti-B18H21 (compound 2) in 67% yield, or, by reaction with …
A series of ultra-efficient blue borane fluorophores
We present the first examples of alkylated derivatives of the macropolyhedral boron hydride,
anti-B18H22, which is the gain medium in the first borane laser. This new series of ten highly …
anti-B18H22, which is the gain medium in the first borane laser. This new series of ten highly …
Unexpected minor products from the thermal auto-fusion of arachno-SB8H12: Luminescent 4-(HS)-syn-B18H21 and 3-(HS)-syn-B18H21
M Ehn, M Litecká, MGS Londesborough - Inorganic Chemistry …, 2023 - Elsevier
The oxidative or thermal fusion of nonaborane and nonaheteroborane species to form
bicluster assemblies, in which two conjoined subclusters share a common edge or triangular …
bicluster assemblies, in which two conjoined subclusters share a common edge or triangular …