Design and applications of water-soluble coordination cages

EG Percástegui, TK Ronson, JR Nitschke - Chemical Reviews, 2020 - ACS Publications
Compartmentalization of the aqueous space within a cell is necessary for life. In similar
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …

Picking the lock of coordination cage catalysis

TK Piskorz, V Martí-Centelles, RL Spicer, F Duarte… - Chemical …, 2023 - pubs.rsc.org
The design principles of metallo-organic assembly reactions have facilitated access to
hundreds of coordination cages of varying size and shape. Many of these assemblies …

[2, 2] Paracyclophanes-based double helicates for constructing artificial light-harvesting systems and white LED device

Z Lian, J He, L Liu, Y Fan, X Chen, H Jiang - Nature Communications, 2023 - nature.com
The construction of efficient artificial light-harvesting systems (ALHSs) is of vital importance
in utilizing solar energy. Herein, we report the non-covalent syntheses of double helicates …

Strategies for binding multiple guests in metal–organic cages

FJ Rizzuto, LKS von Krbek, JR Nitschke - Nature Reviews Chemistry, 2019 - nature.com
The binding of multiple guests by a single entity can lead to new modes of host–guest
interactions and thus new applications in, for example, catalysis and sensing. With the aim of …

Enantioselective fullerene functionalization through stereochemical information transfer from a self-assembled cage

Z Lu, TK Ronson, AW Heard, S Feldmann… - Nature Chemistry, 2023 - nature.com
The regioselective functionalization of C60 remains challenging, while the enantioselective
functionalization of C60 is difficult to explore due to the need for complex chiral tethers or …

Water-soluble self-assembled cage with triangular metal–metal-bonded units enabling the sequential selective separation of alkanes and isomeric molecules

LJ Wang, S Bai, YF Han - Journal of the American Chemical …, 2022 - ACS Publications
The selective separation of structurally similar aliphatic/aromatic hydrocarbons is an
essential goal in industrial processes. In this study, we report the synthesis of a water …

Self-assembled coordination cages based on banana-shaped ligands

M Han, DM Engelhard, GH Clever - Chemical Society Reviews, 2014 - pubs.rsc.org
The combination of pyridyl ligands and square-planar Pd (II) or Pt (II) cations has proven to
be a very reliable recipe for the realization of supramolecular self-assemblies. This tutorial …

Emissive platinum (II) cages with reverse fluorescence resonance energy transfer for multiple sensing

Z Zhang, Z Zhao, L Wu, S Lu, S Ling, G Li… - Journal of the …, 2020 - ACS Publications
It is quite challenging to realize fluorescence resonance energy transfer (FRET) between
two chromophores with specific positions and directions. Herein, through the self-assembly …

Highly emissive perylene diimide-based metallacages and their host–guest chemistry for information encryption

Y Hou, Z Zhang, S Lu, J Yuan, Q Zhu… - Journal of the …, 2020 - ACS Publications
Here we report two highly emissive perylene diimide (PDI)-based metallacages and explore
their complexation with polycyclic aromatic hydrocarbons, such as pyrene, triphenylene, and …

Bent anthracene dimers as versatile building blocks for supramolecular capsules

M Yoshizawa, L Catti - Accounts of chemical research, 2019 - ACS Publications
Conspectus This Account provides a comprehensive summary of our 1-decade-long
investigations into bent anthracene dimers as versatile building blocks for supramolecular …