Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …

Synthetic organic electrosynthesis has grown in the past few decades by achieving many
valuable transformations for synthetic chemists. Although electrocatalysis has been popular …

Catalytic C (sp3)–H functionalization has provided enormous opportunities to construct
organic molecules, facilitating the derivatization of complex pharmaceutical compounds …

We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

Abstract Frustrated Lewis pairs (FLPs) are well documented for the activation of small
molecules such as dihydrogen and carbon dioxide,,–. Although canonical FLP chemistry is …

Hydrogen-atom transfer (HAT) provides straightforward methods to generate open-shell
radical intermediates from RH (R= C, Si, etc.) bonds and offers unique opportunities for …

Value-added chemicals, fuels, and pharmaceuticals synthesized by organic transformation
from raw materials via catalytic techniques have attracted enormous attention in the past few …

Utilizing catalytic CuCl2 we report the functionalization of numerous feedstock chemicals via
the coupling of unactivated C (sp3)–H bonds with electron-deficient olefins. The active …

Conspectus In recent years, the development of light-driven reactions has contributed
numerous advances in synthetic organic chemistry. A particularly active research area …

The selective functionalization of alkanes has long been recognized as a prominent
challenge and an arduous task in organic synthesis. Hydrogen atom transfer (HAT) …