Applications of macrocycle-based solid-state host–guest chemistry

H Zhu, L Chen, B Sun, M Wang, H Li… - Nature Reviews …, 2023 - nature.com
Macrocyclic molecules have been used in various fields owing to their guest binding
properties. Macrocycle-based host–guest chemistry in solution can allow for precise control …

Conjugated nanohoops incorporating donor, acceptor, hetero‐or polycyclic aromatics

M Hermann, D Wassy, B Esser - Angewandte Chemie, 2021 - Wiley Online Library
In the last 13 years several synthetic strategies were developed that provide access to [n]
cycloparaphenylenes ([n] CPPs) and related conjugated nanohoops. A number of potential …

An unexpected dual-emissive luminogen with tunable aggregation-induced emission and enhanced chiroptical property

X Zhang, H Liu, G Zhuang, S Yang, P Du - Nature Communications, 2022 - nature.com
In the literature, organic materials with both aggregation-induced emission (AIE) and
aggregation-caused quenching (ACQ) effects that can emit with multiple bands both in the …

Synthesis of π-conjugated chiral organoborane macrocycles with blue to near-infrared emissions and the diradical character of cations

F Zhao, J Zhao, H Liu, Y Wang, J Duan… - Journal of the …, 2023 - ACS Publications
Highly emissive π-conjugated macrocycles with tunable circularly polarized luminescence
(CPL) have sparked theoretical and synthetic interests in recent years. Herein, we report a …

Circularly Polarized Luminescence in Chiral π‐Conjugated Macrocycles

M Hasegawa, Y Nojima, Y Mazaki - ChemPhotoChem, 2021 - Wiley Online Library
The design and synthesis of novel π‐conjugated macrocycles have been an attractive topic
in synthetic chemistry and material and supramolecular chemistry. The distortion caused by …

Lemniscular carbon nanohoops with contiguous conjugation from planar chiral [2.2] paracyclophane: influence of the regioselective synthesis on topological chirality

J He, MH Yu, Z Lian, YQ Fan, SZ Guo, XN Li… - Chemical …, 2023 - pubs.rsc.org
We report herein the regioselective synthesis of all-carbon lemniscular nanohoops bis-po-
CC and bis-pm-TC by the rational control of ring closures at the different positions of planar …

Circularly polarized luminescence in a Möbius helicene carbon nanohoop

J Malinčík, S Gaikwad, JP Mora‐Fuentes… - Angewandte Chemie …, 2022 - Wiley Online Library
We present the first helicene carbon nanoohop that integrates a [6] helicene into [7]
cycloparaphenylene. The [6] helicene endows the helicene carbon nanohoop with …

Overcrowded Ethylene-Bridged Nanohoop Dimers: Regioselective Synthesis, Multiconfigurational Electronic States, and Global Hückel/Möbius Aromaticity

K Li, Z Xu, J Xu, T Weng, X Chen, S Sato… - Journal of the …, 2021 - ACS Publications
The design and preparation of molecular systems with multiple geometric and electronic
configurations are the cornerstones for multifunctional materials with stimuli-responsive …

A Conjugated Figure‐of‐Eight Oligoparaphenylene Nanohoop with Adaptive Cavities Derived from Cyclooctatetrathiophene Core

L Zhan, C Dai, G Zhang, J Zhu, S Zhang… - Angewandte Chemie …, 2022 - Wiley Online Library
A fully conjugated figure‐of‐eight nanohoop is presented with facile synthesis. The
molecule's lemniscular skeleton features the combination of two strained …

Carbon Nanorings and Nanobelts: Material Syntheses, Molecular Architectures, and Applications

R Zhang, D An, J Zhu, X Lu, Y Liu - Advanced Functional …, 2023 - Wiley Online Library
Carbon nanorings (CNRs) and carbon nanobelts (CNBs) of various sizes and innovative
molecular architectures have ushered improvement in research in recent years. This serves …