Synthesis and properties of polymerized ionic liquids

A Eftekhari, T Saito - European Polymer Journal, 2017 - Elsevier
Polymerization of ionic liquids results in the formation of ionic polymers, which are called
poly (ionic liquid) s or polymerized ionic liquids (PIL). This is a brand new form of ionicity in …

Dilute polyelectrolyte solutions: recent progress and open questions

CG Lopez, A Matsumoto, AQ Shen - Soft Matter, 2024 - pubs.rsc.org
Polyelectrolytes are a class of polymers possessing ionic groups on their repeating units.
Since counterions can dissociate from the polymer backbone, polyelectrolyte chains are …

Perspectives for polymer electrolytes: a view from fundamentals of ionic conductivity

V Bocharova, AP Sokolov - Macromolecules, 2020 - ACS Publications
We present a brief overview of current developments in the field of polymer electrolytes, with
the focus on single-ion conducting polymers. The latter have significant advantages relative …

Decoupling segmental relaxation and ionic conductivity for lithium-ion polymer electrolytes

D Bresser, S Lyonnard, C Iojoiu, L Picard… - … Systems Design & …, 2019 - pubs.rsc.org
The use of polymer electrolytes instead of liquid organic systems is considered key for
enhancing the safety of lithium batteries and may, in addition, enable the transition to high …

On order and disorder in polymer electrolytes

D Golodnitsky, E Strauss, E Peled… - Journal of The …, 2015 - iopscience.iop.org
This contribution presents an overview of more than three-decades-long studies of the
structure and mechanism of ion conduction in polyethylene-oxide-based solid polymer …

Ion transport in small-molecule and polymer electrolytes

CY Son, ZG Wang - The Journal of Chemical Physics, 2020 - pubs.aip.org
Solid-state polymer electrolytes and high-concentration liquid electrolytes, such as water-in-
salt electrolytes and ionic liquids, are emerging materials to replace the flammable organic …

Mechanisms underlying ion transport in polymerized ionic liquids

S Mogurampelly, JR Keith… - Journal of the American …, 2017 - ACS Publications
We report the results of atomistic molecular dynamics simulations informed by quantum-
mechanically parametrized force fields, which identify the mechanisms underlying ion …

Effect of molecular weight on the ion transport mechanism in polymerized ionic liquids

F Fan, W Wang, AP Holt, H Feng, D Uhrig, X Lu… - …, 2016 - ACS Publications
The unique properties of ionic liquids (ILs) have made them promising candidates for
electrochemical applications. Polymerization of the corresponding ILs results in a new class …

Effects of ion size and dielectric constant on ion transport and transference number in polymer electrolytes

KH Shen, LM Hall - Macromolecules, 2020 - ACS Publications
Salt-doped polymers without added solvents have the potential to be nonflammable, robust
electrolytes for batteries but suffer from low ion conductivity. Using bulky anions with …

polymer/ceramic interface barriers: the fundamental challenge for advancing composite solid electrolytes for Li-ion batteries

Y Horowitz, M Lifshitz, A Greenbaum… - Journal of The …, 2020 - iopscience.iop.org
Composite-solid electrolytes, in which ion-conducting polymers are combined with
superionic ceramics, could revolutionize electrochemical-energy-storage devices enabling …