Where biology and traditional polymers meet: The potential of associating sequence-defined polymers for materials science

AJ DeStefano, RA Segalman, EC Davidson - Jacs Au, 2021 - ACS Publications
Polymers with precisely defined monomeric sequences present an exquisite tool for
controlling material properties by harnessing both the robustness of synthetic polymers and …

Styrenic Block copolymer‐based thermoplastic elastomers in smart applications: Advances in synthesis, microstructure, and structure–property relationships—a …

P Maji, K Naskar - Journal of Applied Polymer Science, 2022 - Wiley Online Library
Styrenic block copolymers (SBC) have been gaining attention as a specialty material in
elastomer and composite industries over an extended period. Its unique segmental …

General route to design polymer molecular weight distributions through flow chemistry

DJ Walsh, DA Schinski, RA Schneider… - Nature …, 2020 - nature.com
The properties of a polymer are known to be intrinsically related to its molecular weight
distribution (MWD); however, previous methodologies of MWD control do not use a design …

Precise control of both dispersity and molecular weight distribution shape by polymer blending

R Whitfield, NP Truong, A Anastasaki - Angewandte Chemie, 2021 - Wiley Online Library
The breadth and the shape of molecular weight distributions can significantly influence
fundamental polymer properties that are critical for various applications. However, current …

Enhanced mechanical properties of aliphatic polyester thermoplastic elastomers through star block architectures

S Liffland, MA Hillmyer - Macromolecules, 2021 - ACS Publications
A series of sustainable aliphatic polyester thermoplastic elastomers (APTPEs) consisting of
multi-arm star polymers with arms of poly (l-lactide)-b-poly (γ-methyl-ε-caprolactone) were …

Designing dynamic materials from dynamic bonds to macromolecular architecture

NDA Watuthanthrige, P Chakma, D Konkolewicz - Trends in Chemistry, 2021 - cell.com
Introducing dynamic and exchangeable bonds can breathe life into polymers by imparting
self-healing, enhanced toughness, or adaptability to the material. Synergies between the …

Shifting boundaries: controlling molecular weight distribution shape for mechanically enhanced thermoplastic elastomers

SI Rosenbloom, BP Fors - Macromolecules, 2020 - ACS Publications
Thermoplastic elastomers (TPEs) based on polystyrene (PS) are commonplace in society.
The elastomeric properties of these materials are often sacrificed to increase mechanical …

A comprehensive platform for the design and synthesis of polymer molecular weight distributions

K Liu, N Corrigan, A Postma, G Moad, C Boyer - Macromolecules, 2020 - ACS Publications
The molecular weight distribution (MWD) has a significant impact on the properties of
polymeric materials; however, the characterization of polymer MWDs has been limited to …

Chromatographic Separation: A Versatile Strategy to Prepare Discrete and Well-Defined Polymer Libraries

EA Murphy, C Zhang, CM Bates… - Accounts of Chemical …, 2024 - ACS Publications
Conspectus The preparation of discrete and well-defined polymers is an emerging strategy
for emulating the remarkable precision achieved by macromolecular synthesis in nature …

Controlling primary chain dispersity in network polymers: elucidating the effect of dispersity on degradation

T Shimizu, R Whitfield, GR Jones, IO Raji… - Chemical …, 2023 - pubs.rsc.org
Although dispersity has been demonstrated to be instrumental in determining many polymer
properties, current synthetic strategies predominantly focus on tailoring the dispersity of …