Where biology and traditional polymers meet: The potential of associating sequence-defined polymers for materials science
Polymers with precisely defined monomeric sequences present an exquisite tool for
controlling material properties by harnessing both the robustness of synthetic polymers and …
controlling material properties by harnessing both the robustness of synthetic polymers and …
Styrenic Block copolymer‐based thermoplastic elastomers in smart applications: Advances in synthesis, microstructure, and structure–property relationships—a …
Styrenic block copolymers (SBC) have been gaining attention as a specialty material in
elastomer and composite industries over an extended period. Its unique segmental …
elastomer and composite industries over an extended period. Its unique segmental …
General route to design polymer molecular weight distributions through flow chemistry
DJ Walsh, DA Schinski, RA Schneider… - Nature …, 2020 - nature.com
The properties of a polymer are known to be intrinsically related to its molecular weight
distribution (MWD); however, previous methodologies of MWD control do not use a design …
distribution (MWD); however, previous methodologies of MWD control do not use a design …
Precise control of both dispersity and molecular weight distribution shape by polymer blending
The breadth and the shape of molecular weight distributions can significantly influence
fundamental polymer properties that are critical for various applications. However, current …
fundamental polymer properties that are critical for various applications. However, current …
Enhanced mechanical properties of aliphatic polyester thermoplastic elastomers through star block architectures
S Liffland, MA Hillmyer - Macromolecules, 2021 - ACS Publications
A series of sustainable aliphatic polyester thermoplastic elastomers (APTPEs) consisting of
multi-arm star polymers with arms of poly (l-lactide)-b-poly (γ-methyl-ε-caprolactone) were …
multi-arm star polymers with arms of poly (l-lactide)-b-poly (γ-methyl-ε-caprolactone) were …
Designing dynamic materials from dynamic bonds to macromolecular architecture
NDA Watuthanthrige, P Chakma, D Konkolewicz - Trends in Chemistry, 2021 - cell.com
Introducing dynamic and exchangeable bonds can breathe life into polymers by imparting
self-healing, enhanced toughness, or adaptability to the material. Synergies between the …
self-healing, enhanced toughness, or adaptability to the material. Synergies between the …
Shifting boundaries: controlling molecular weight distribution shape for mechanically enhanced thermoplastic elastomers
SI Rosenbloom, BP Fors - Macromolecules, 2020 - ACS Publications
Thermoplastic elastomers (TPEs) based on polystyrene (PS) are commonplace in society.
The elastomeric properties of these materials are often sacrificed to increase mechanical …
The elastomeric properties of these materials are often sacrificed to increase mechanical …
A comprehensive platform for the design and synthesis of polymer molecular weight distributions
The molecular weight distribution (MWD) has a significant impact on the properties of
polymeric materials; however, the characterization of polymer MWDs has been limited to …
polymeric materials; however, the characterization of polymer MWDs has been limited to …
Chromatographic Separation: A Versatile Strategy to Prepare Discrete and Well-Defined Polymer Libraries
Conspectus The preparation of discrete and well-defined polymers is an emerging strategy
for emulating the remarkable precision achieved by macromolecular synthesis in nature …
for emulating the remarkable precision achieved by macromolecular synthesis in nature …
Controlling primary chain dispersity in network polymers: elucidating the effect of dispersity on degradation
Although dispersity has been demonstrated to be instrumental in determining many polymer
properties, current synthetic strategies predominantly focus on tailoring the dispersity of …
properties, current synthetic strategies predominantly focus on tailoring the dispersity of …