Self assembled monolayers on silicon for molecular electronics

DK Aswal, S Lenfant, D Guérin, JV Yakhmi… - Analytica chimica …, 2006 - Elsevier
We present an overview of various aspects of the self-assembly of organic monolayers on
silicon substrates for molecular electronics applications. Different chemical strategies …

Wet chemical routes to the assembly of organic monolayers on silicon surfaces via the formation of Si–C bonds: Surface preparation, passivation and functionalization

S Ciampi, JB Harper, JJ Gooding - Chemical Society Reviews, 2010 - pubs.rsc.org
Organic functionalization of non-oxidized silicon surfaces, while allowing for robust chemical
passivation of the inorganic substrate, is intended and expected to broaden the chemical …

Formation of Al13I-: Evidence for the Superhalogen Character of Al13

DE Bergeron, AW Castleman Jr, T Morisato… - Science, 2004 - science.org
Al13–is a cluster known for the pronounced stability that arises from coincident closures of
its geometric and electronic shells. We present experimental evidence for a very stable …

Functionalization of acetylene-terminated monolayers on Si (100) surfaces: a click chemistry approach

S Ciampi, T Böcking, KA Kilian, M James, JB Harper… - Langmuir, 2007 - ACS Publications
In this article, we report the functionalization of alkyne-terminated alkyl monolayers on Si
(100) using “click” chemistry, specifically, the Cu (I)-catalyzed Huisgen 1, 3-dipolar …

The surface as molecular reagent: organic chemistry at the semiconductor interface

MA Filler, SF Bent - Progress in surface science, 2003 - Elsevier
Methods for the incorporation of organic functionality onto semiconductor surfaces have
seen immense progress in recent years. Of the multiple methods developed, the direct …

Tailoring the structure of thin film nanocomposite membranes to achieve seawater RO membrane performance

ML Lind, D Eumine Suk, TV Nguyen… - … science & technology, 2010 - ACS Publications
Herein we report on the formation and characterization of pure polyamide thin film
composite (TFC) and zeolite− polyamide thin film nanocomposite (TFN) reverse osmosis …

Ultrafast electron crystallography of interfacial water

CY Ruan, VA Lobastov, F Vigliotti, S Chen, AH Zewail - Science, 2004 - science.org
We report direct determination of the structures and dynamics of interfacial water on a
hydrophilic surface with atomic-scale resolution using ultrafast electron crystallography. On …

Synthesis and modification of silicon nanosheets and other silicon nanomaterials

H Okamoto, Y Sugiyama… - Chemistry–A European …, 2011 - Wiley Online Library
Silicon nanomaterials and nanostructures exhibit different properties from those of bulk
silicon materials based on quantum confinement effects. They are expected to lead to the …

Synthesis and optical properties of monolayer organosilicon nanosheets

Y Sugiyama, H Okamoto, T Mitsuoka… - Journal of the …, 2010 - ACS Publications
The synthesis of silicon nanosheets for fabricating electronic devices, without using
conventional vacuum processes and vapor deposition, is challenging and is anticipated to …

Comparison of the electrical properties and chemical stability of crystalline silicon (111) surfaces alkylated using grignard reagents or olefins with Lewis acid catalysts

LJ Webb, NS Lewis - The Journal of Physical Chemistry B, 2003 - ACS Publications
Four methods were used to functionalize crystalline Si (111) surfaces with alkyl groups (C n
H2 n+ 1, n= 1, 2, 6, 8): chlorination with PCl5 followed by alkylation with C n H2 n+ 1MgX …