[LIVRE][B] Nonadiabatic transition: concepts, basic theories and applications

H Nakamura - 2012 - books.google.com
Nonadiabatic transition is a highly multidisciplinary concept and phenomenon, constituting a
fundamental mechanism of state and phase changes in various dynamical processes of …

Landau-Zener model: Effects of finite coupling duration

NV Vitanov, BM Garraway - Physical Review A, 1996 - APS
We present the generalization of the Landau-Zener model for a constant coupling of a finite
duration. The exact evolution matrix is expressed in terms of sums of by-products of …

Predicting kinetics and dynamics of spin-dependent processes

ID Dergachev, VD Dergachev, M Rooein… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Predicting mechanisms and rates of nonadiabatic spin-dependent processes
including photoinduced intersystem crossings, thermally activated spin-forbidden reactions …

Theory of nonadiabatic transition for general two‐state curve crossing problems. I. Nonadiabatic tunneling case

C Zhu, H Nakamura - The Journal of chemical physics, 1994 - pubs.aip.org
Based on the achievements for the linear potential model, new accurate and compact
formulas are established for general two‐state nonadiabatic tunneling type curve crossing …

Future perspectives of nonadiabatic chemical dynamics

S Nanbu, T Ishida, H Nakamura - Chemical Science, 2010 - pubs.rsc.org
A variety of chemical phenomena are governed by non-adiabatic transitions at conical
intersections of potential energy surfaces, if not directly, but indirectly in the midst of the …

Theory of nonadiabatic transition for general two‐state curve crossing problems. II. Landau–Zener case

C Zhu, H Nakamura - The Journal of chemical physics, 1995 - pubs.aip.org
New accurate and compact formulas are established for general two‐state curve crossing
problems in the Landau–Zener case, in which the two diabatic potentials cross with the …

[LIVRE][B] Chemical Theory Beyond the Born-Oppenheimer Paradigm: Nonadiabatic Electronic and Nuclear Dynamics in Chemical Reactions

K Takatsuka, Y Arasaki, T Yonehara, K Hanasaki - 2014 - books.google.com
This unique volume offers a clear perspective of the relevant methodology relating to the
chemical theory of the next generation beyond the Born-Oppenheimer paradigm. It bridges …

[PDF][PDF] Nonadiabatic transitions due to curve crossings: complete solutions of the landau‐zener‐stueckelberg problems and their applications

C Zhu, Y Teranishi, H Nakamura - Advances in Chemical Physics, 2001 - academia.edu
OFTHELANDAU-ZENER-STUECKELBERG Page 1 NONADIABATIC TRANSITIONS DUE TO
CURVE CROSSINGS: COMPLETE SOLUTIONS PROBLEMS AND THEIR APPLICATIONS …

Intersystem crossing in tunneling regime: T 1→ S 0 relaxation in thiophosgene

AO Lykhin, SA Varganov - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
The T1 excited state relaxation in thiophosgene has attracted much attention as a relatively
simple model for the intersystem crossing (ISC) transitions in polyatomic molecules. The …

[HTML][HTML] Nonadiabatic instanton rate theory beyond the golden-rule limit

G Trenins, JO Richardson - The Journal of Chemical Physics, 2022 - pubs.aip.org
Fermi's golden rule (GR) describes the leading-order behavior of the reaction rate as a
function of the diabatic coupling. Its asymptotic (ℏ→ 0) limit is the semiclassical golden-rule …