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Ensemble effect for single-atom, small cluster and nanoparticle catalysts
A large family of heterogeneous catalytic reactions require active sites with more than one
metal atom, that is, an ensemble of metal atoms. The ensemble requirement, which refers to …
metal atom, that is, an ensemble of metal atoms. The ensemble requirement, which refers to …
Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?
F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …
with focus on how they contribute to the improvement of selectivity in heterogeneous …
Single-atom catalysts across the periodic table
Isolated atoms featuring unique reactivity are at the heart of enzymatic and homogeneous
catalysts. In contrast, although the concept has long existed, single-atom heterogeneous …
catalysts. In contrast, although the concept has long existed, single-atom heterogeneous …
Single-atom catalysts based on the metal–oxide interaction
Metal atoms dispersed on the oxide supports constitute a large category of single-atom
catalysts. In this review, oxide supported single-atom catalysts are discussed about their …
catalysts. In this review, oxide supported single-atom catalysts are discussed about their …
Electronic metal–support interaction of single‐atom catalysts and applications in electrocatalysis
The electronic metal–support interaction (EMSI), which acts as a bridge between theoretical
electronic study and the design of heterogenous catalysts, has attracted much attention …
electronic study and the design of heterogenous catalysts, has attracted much attention …
First-principles design of a single-atom–alloy propane dehydrogenation catalyst
The complexity of heterogeneous catalysts means that a priori design of new catalytic
materials is difficult, but the well-defined nature of single-atom–alloy catalysts has made it …
materials is difficult, but the well-defined nature of single-atom–alloy catalysts has made it …
Single-atom alloy catalysis
Single-atom alloys (SAAs) play an increasingly significant role in the field of single-site
catalysis and are typically composed of catalytically active elements atomically dispersed in …
catalysis and are typically composed of catalytically active elements atomically dispersed in …
Noble-metal based random alloy and intermetallic nanocrystals: syntheses and applications
Precise control over the size, shape, composition, structure, and crystal phase of random
alloy and intermetallic nanocrystals has been intensively explored in technologically …
alloy and intermetallic nanocrystals has been intensively explored in technologically …
Single-atom alloy catalysts: structural analysis, electronic properties and catalytic activities
Monometallic catalysts, in particular those containing noble metals, are frequently used in
heterogeneous catalysis, but they are expensive, rare and the ability to tailor their structures …
heterogeneous catalysis, but they are expensive, rare and the ability to tailor their structures …
Dilute alloys based on Au, Ag, or Cu for efficient catalysis: from synthesis to active sites
The development of new catalyst materials for energy-efficient chemical synthesis is critical
as over 80% of industrial processes rely on catalysts, with many of the most energy-intensive …
as over 80% of industrial processes rely on catalysts, with many of the most energy-intensive …