Heterobimetallic complexes are studied for their ability to mimic biological systems as well
as active sites in heterogeneous catalysts. While specific interest in early/late …

The chemistry of early transition element clusters with π-donor ligands is growing rapidly.
We review the syntheses of these compounds, with an emphasis on progress in the last 6 …

In the field of metal–metal bonding, the occurrence of stable, multiple bonds between
different transition metals is uncommon, and is largely unknown for different first-row metals …

Metal–metal multiple bonds have been an intense area of focus in inorganic chemistry for
many decades as a result of their fundamentally interesting bonding properties, as well as …

Eleven experimentally characterized complexes containing heterobimetallic bonds between
elements of the f‐block and other elements were examined by quantum chemical …

It is of great importance to study the mechanisms to activate dinitrogen (N2), the very inert
molecule, under mild conditions. Gas-phase metal clusters are being actively generated to …

Metal–metal bonded species involving lanthanides are intriguing but rare. The recently
reported salt metathesis reaction of an Al anion and SmI2 (thf) 2 yields novel heterometallic …

It is of great importance to find catalysts for the nitrogen reduction reaction (NRR) with high
stability and reactivity. A series of M3 clusters (M= Ti, Zr, V, and Nb) supported on sumanene …

Multiple metal–metal bonds are uncommon in heterobimetallic complexes.[1] Rare
examples of heterobimetallics with short metal–metal bonds include [TiRh …

The interaction of free-base triarylcorroles with Re2 (CO) 10 in 1, 2-dichlorobenzene in the
presence of 2, 6-lutidine at 180° C under strict anerobic conditions afforded approximately …