Coordination chemistry-driven approaches to rare earth element separations

RF Higgins, KP Ruoff, A Kumar… - Accounts of Chemical …, 2022 - ACS Publications
Conspectus Current projections for global mining indicate that unsustainable practices will
cause supply problems for many elements, called critical raw materials, in the next 20 years …

Stabilization of the oxidation state+ IV in siloxide‐supported terbium compounds

AR Willauer, CT Palumbo, R Scopelliti… - Angewandte Chemie …, 2020 - Wiley Online Library
The synthesis of lanthanides other than cerium in the oxidation state+ IV has remained a
desirable but unmet target until recently, when two examples of TbIV with saturated …

[HTML][HTML] Exploiting end-of-life lamps fluorescent powder e-waste as a secondary resource for critical rare earth metals

AB Patil, M Tarik, RPWJ Struis, C Ludwig - Resources, Conservation and …, 2021 - Elsevier
The consensus is growing for the UN sustainable development goals regarding responsible
consumption, production, and climate actions. Because of growth towards a digital society …

Modulating metal-centered dimerization of a lanthanide chaperone protein for separation of light lanthanides

WB Larrinaga, JJ Jung, CY Lin, AK Boal… - Proceedings of the …, 2024 - pnas.org
Elucidating details of biology's selective uptake and trafficking of rare earth elements,
particularly the lanthanides, has the potential to inspire sustainable biomolecular …

Magnetic field directed rare‐earth separations

RF Higgins, T Cheisson, BE Cole… - Angewandte …, 2020 - Wiley Online Library
The separation of rare‐earth ions from one another is challenging due to their chemical and
physical similarities. Nearly all rare‐earth separations rely upon small changes in ionic radii …

Selective Crystallization of a Highly Radiation-Resistant Isonicotinic Acid-Based Metal–Organic Framework as a Primary Actinide Waste Form

K Lv, M Patzschke, J März, E Bazarkina… - ACS Materials …, 2023 - ACS Publications
Isonicotinic acid (INA), as a prototypical N, O-donor bifunctional ligand, has demonstrated its
ability to differentiate Th4+ from representative ions for products in spent nuclear fuels (Cs+ …

High-throughput screening for discovery of benchtop separations systems for selected rare earth elements

JJM Nelson, T Cheisson, HJ Rugh, MR Gau… - Communications …, 2020 - nature.com
Rare earth (RE) elements (scandium, yttrium, and the lanthanides) are critical for their role in
sustainable energy technologies. Problems with their supply chain have motivated research …

The earlier the better: Structural analysis and separation of lanthanides with pyrroloquinoline quinone

H Lumpe, A Menke, C Haisch, P Mayer… - … A European Journal, 2020 - Wiley Online Library
Lanthanides (Ln) are critical raw materials, however, their mining and purification have a
considerable negative environmental impact and sustainable recycling and separation …

Syntheses and Characterization of Tetrazolate-Based Lanthanide Compounds and Selective Crystallization Separation of Neodymium and Dysprosium

Z Bai, B Scheibe, JM Sperling… - Inorganic …, 2022 - ACS Publications
Selective crystallization offers new opportunities for separating neodymium and dysprosium,
which are considerably important in permanent magnets. Two water-soluble nitrogen-rich …

Understanding molecular factors that determine performance in the rare earth (TriNOx) separations system

BE Cole, T Cheisson, JJM Nelson… - ACS Sustainable …, 2020 - ACS Publications
Rare earth metal complexes of the proligand H3TriNOx ([(2-t BuNOH) C6H3CH2] 3N) have
been shown to afford separations of simple mixtures of rare earth metal salts. In particular …