Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …

Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

Endogenous photosensitizers play a critical role in both beneficial and harmful light-induced
transformations in biological systems. Understanding their mode of action is essential for …

Cross-coupling platforms are traditionally built around a sequence of closed-shell steps,
such as oxidative addition, transmetalation, and reductive elimination. Herein, we describe a …

Bicyclo [2.1. 1] hexanes have become increasingly popular building blocks in medicinal
chemistry as bridged scaffolds that provide unexplored chemical space. We herein report a …

A highly selective and divergent synthesis enables access to various molecules and has
garnered broad interest from not only organic chemists but also medicinal chemists and …

Due to their strong covalent bonds and low reduction potentials, activating inert substrates is
challenging. Recent advances in photoredox catalysis offered a number of solutions, each of …

Herein, we report the rational design of a modular dual photoredox and cobalt catalysis
paradigm for the difunctionalization of unsaturated hydrocarbons, unlocking the synthesis of …

Herein, we present the discovery and development of the first photoredox-catalyzed alkoxy
diazomethylation of alkenes with hypervalent iodine reagents and alcohols. This …