Aqueous interfaces in chemical separations

A Uysal - Langmuir, 2023 - ACS Publications
Chemical separations play a vital role in refinery and reprocessing of critical materials, such
as platinum group metals, rare earths, and actinides. The choice of separation system─ …

Antagonistic role of aqueous complexation in the solvent extraction and separation of rare earth ions

P Sun, EA Binter, Z Liang, MA Brown… - ACS Central …, 2021 - ACS Publications
Solvent extraction is used widely for chemical separations and environmental remediation.
Although the kinetics and efficiency of this process rely upon the formation of ion–extractant …

Origins of clustering of metalate–extractant complexes in liquid–liquid extraction

S Nayak, RR Kumal, Z Liu, B Qiao… - … Applied Materials & …, 2021 - ACS Publications
Effective and energy-efficient separation of precious and rare metals is very important for a
variety of advanced technologies. Liquid–liquid extraction (LLE) is a relatively less energy …

Elucidating trivalent ion adsorption at floating carboxylic acid monolayers: Charge reversal or water reorganization?

S Nayak, RR Kumal, SE Lee… - The Journal of Physical …, 2023 - ACS Publications
We study the adsorption of trivalent neodymium on floating arachidic acid films at the air–
water interface by two complementary surface specific probes, sum frequency generation …

Iron (III) speciation observed at aqueous and glycerol surfaces: vibrational sum frequency and X-ray

L Lin, J Husek, S Biswas, SM Baumler… - Journal of the …, 2019 - ACS Publications
Aqueous solutions of FeCl3 have been widely studied to shed light on a number of
processes from dissolution, mineralization, biology, electrocatalysis, corrosion, to microbial …

Effects of ion adsorption on graphene oxide films and interfacial water structure: A molecular-scale description

AJ Carr, RR Kumal, W Bu, A Uysal - Carbon, 2022 - Elsevier
Graphene oxide is a promising, emerging separation material, as it is durable, dispersible in
water, and has naturally forming functional groups. Bulk studies using graphene oxide flakes …

Noncoordinating secondary sphere ion modulates supramolecular clustering of lanthanides

DM Driscoll, H Liu, B Reinhart, I Popovs… - The Journal of …, 2022 - ACS Publications
The role of counterions in molecular recognition of lanthanides is underexplored, especially
when they exhibit weak interactions with the metal cations. Here, we report a complementary …

Development of heavy element chemistry at interfaces: observing actinide complexes at the oil/water interface in solvent extraction by nonlinear vibrational …

R Kusaka, M Watanabe - The Journal of Physical Chemistry …, 2022 - ACS Publications
Understanding the chemistry of elements at the bottom of the periodic table is a challenging
goal in chemistry. Observing actinide species at interfaces by using interface-selective …

Convenient confinement: Interplay of solution conditions and graphene oxide film structure on rare earth separations

AJ Carr, SE Lee, RR Kumal, W Bu… - ACS Applied Materials & …, 2022 - ACS Publications
Graphene oxide (GO) membranes are excellent candidates for a range of separation
applications, including rare earth segregation and radionuclide decontamination …

Anions enhance rare earth adsorption at negatively charged surfaces

S Nayak, K Lovering, W Bu, A Uysal - The journal of physical …, 2020 - ACS Publications
Anions are expected to be repelled from negatively charged surfaces. At aqueous interfaces,
however, ion-specific effects can dominate over direct electrostatic interactions. Using …