Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Octacyanidometallates have been successfully employed in the design of heterometallic
coordination systems offering a spectacular range of desired physical properties with great …

Magnetic bistable materials that feature magnetic hysteresis are comparable to elementary
binary units and promising for application in switches and memory devices. In this work, we …

Metal‐to‐metal charge transfer (MMCT) describes electron transfer between metal ions, to
generate valence isomers with markedly different electronic configurations. In particular …

Pristine metal–organic frameworks (MOFs) have received much attention in recent years
due to their high specific surface areas, large porosity, excellent pore size distributions …

Addressing molecular bistability as a function of external stimuli, especially in spin-crossover
(SCO) and metal-to-metal electron transfer (MMET) systems, has seen a surge of interest in …

Bistable and stimuli‐responsive molecule‐based materials are promising candidates for the
development of molecular switches and sensors for future technologies. The CN‐bridged …

Polynuclear coordination clusters (PCCs) provide considerable design capabilities towards
various functions based on structural non-rigidity and spin state transitions, optical …

Molecular solid solutions of metal clusters containing different metal centers with well-
defined structures can accurately regulate the HOMO-LUMO gap, but are rarely available …

Exploring methods for assembling functional materials at the molecular level may yield
functional expressions derived from the assembly method. This study developed novel …