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Self-assembly of colloidal nanocrystals: from intricate structures to functional materials
Chemical methods developed over the past two decades enable preparation of colloidal
nanocrystals with uniform size and shape. These Brownian objects readily order into …
nanocrystals with uniform size and shape. These Brownian objects readily order into …
Polymer brushes: Synthesis, characterization, properties and applications
Polymer brushes are thin polymer films in which the individual polymer chains are tethered
by one chain end to a solid interface. The bulk and solution properties of these highly …
by one chain end to a solid interface. The bulk and solution properties of these highly …
Brush-modified materials: Control of molecular architecture, assembly behavior, properties and applications
Recent progress in surface-initiated polymerization enables the deliberate polymer
modification of nanoscopic surfaces with high levels of precision. This has given rise to the …
modification of nanoscopic surfaces with high levels of precision. This has given rise to the …
Organic nanoparticles with tunable size and rigidity by hyperbranching and cross-linking using microemulsion ATRP
Unlike inorganic nanoparticles, organic nanoparticles (oNPs) offer the advantage of “interior
tailorability,” thereby enabling the controlled variation of physicochemical characteristics and …
tailorability,” thereby enabling the controlled variation of physicochemical characteristics and …
Effect of graft molecular weight and density on the mechanical properties of polystyrene-grafted cellulose nanocrystal films
Polymer-grafted nanoparticle (PGN) films were prepared from polystyrene (PS) grafted to
rodlike cellulose nanocrystals (MxG-CNC-g-PS) with a controllable grafting density (0.03 …
rodlike cellulose nanocrystals (MxG-CNC-g-PS) with a controllable grafting density (0.03 …
Topologically induced heterogeneity in gradient copolymer brush particle materials
A facile synthetic route toward silica brush particles with random and gradient copolymer
grafts comprised of n-butyl acrylate (BA) and methyl methacrylate (MMA) using surface …
grafts comprised of n-butyl acrylate (BA) and methyl methacrylate (MMA) using surface …
Control of Phase Morphology of Binary Polymer Grafted Nanoparticle Blend Films via Direct Immersion Annealing
While the phase separation of binary mixtures of chemically different polymer-grafted
nanoparticles (PGNPs) is observed to superficially resemble conventional polymer blends …
nanoparticles (PGNPs) is observed to superficially resemble conventional polymer blends …
Disentangling the role of chain conformation on the mechanics of polymer tethered particle materials
The linear elastic properties of isotropic materials of polymer tethered nanoparticles (NPs)
are evaluated using noncontact Brillouin light spectroscopy. While the mechanical …
are evaluated using noncontact Brillouin light spectroscopy. While the mechanical …
Structure–property relationships of polymer-grafted nanospheres for designing advanced nanocomposites
Polymer-grafted nanoparticles are an important component of many classes of polymer
nanocomposites. Here, we review the structure of polymer brushes on spherical …
nanocomposites. Here, we review the structure of polymer brushes on spherical …
Materials by design for stiff and tough hairy nanoparticle assemblies
Matrix-free polymer-grafted nanocrystals, called assembled hairy nanoparticles (aHNPs),
can significantly enhance the thermomechanical performance of nanocomposites by …
can significantly enhance the thermomechanical performance of nanocomposites by …