The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with
respect to “traditional” precious metal catalyzed transformations. The introduction of …

Cobalt has become increasingly attractive in homogeneous catalysis because of its unique
characteristics and outstanding catalytic performance in addition to being cheap and earth …

Novel-substituted pyrrolidine derivatives are widely used in drugs and bioactive molecules.
The efficient synthesis of these valuable skeletons, especially enantiopure derivatives, is still …

Strategies to achieve spatiotemporal regulation of pre‐existing alkenes via external stimuli
are essential given the ubiquity of feedstock olefins in chemistry and their downstream …

Cobalt–N-heterocyclic carbene (NHC) complexes have emerged as an attractive class of 3d
transition metal catalysts for a broad range of chemical processes, including cross-coupling …

Non‐noble metal catalysts based on pincer type compounds are of special interest for
organometallic chemistry and organic synthesis. Next to iron and manganese, currently …

Bimetallic catalysts of nickel (0) with a trivalent rare-earth ion or Ga (III), NiML3 (where L is
[iPr2PCH2NPh]−, and M is Sc, Y, La, Lu, or Ga), were investigated for the selective …

The hydrogenation of alkynes allows the synthesis of olefins, which are important feedstock
for the materials, pharmaceutical, and petrochemical industry. Thus, methods that enable …

cis-Delivery of H2 to the π-system of an unsaturated substrate is the canonical course of
metal catalyzed hydrogenation reactions. The semireduction of internal alkynes with the aid …

The selective hydrogenation of nitriles to primary amines using a bench-stable cobalt
precatalyst under 4 atm of H2 is reported herein. The catalyst precursor was reduced in situ …