With the rapid development of science and technology and the trend of multidisciplinary
pervasion, POM-based TM–RE heterometallic chemistry (POM= polyoxometalate, TM …

Lanthanopolyoxometalates (LnPOMs), obtained through the coordination of
polyoxometalates (POMs) and lanthanide ions (Ln), have received extraordinary interest of …

The research on heterometallic 3d-4f polyoxometalates has made immense progress over
the last decade with a larger number of structures being reported every year until the present …

The mono-lacunary Keggin-type polyoxometalate (MLKP)-based crystalline materials are of
significant interest due to their remarkable structural characteristics and functionalities …

Heterometallic polyoxotungstates (HMPOTs) are still a challenging and attractive materials
in polyoxometalate chemistry despite having generated remarkable interest in recent years …

Three organic–inorganic hybrid copper–lanthanide heterometallic germanotungstates,{[Cu
(en) 2 (H2O)][Cu3Eu (en) 3 (OH) 3 (H2O) 2](α-GeW11O39)} 2· 11H2O (1),{[Cu (en) 2 …

A series of organic–inorganic hybrid lacunary Keggin silicotungstate 3d-4f heterometallic
derivatives,{[Cu (en) 2] 1.5 Ln [(α-SiW11O39) 2]} 220–[Ln= GdIII for 1, TbIII for 2, DyIII for 3 …

Four types of organic–inorganic hybrids Na [Cu (en) 2 (H2O)] 4 [Cu (en) 2] 2 [Cu (H2O) 4]
0.5 {Cu (en) 2 [H2CeIV (α-AsW11O39) 2] 2}· 10H2O (1), Na3 [Cu (en) 2 (H2O)][Cu (en) 2] 1.5 …

Five rare‐earth–transition‐metal (RE–TM) heterometal organic–inorganic hybrids based on
Keggin‐type silicotungstates and mixed ligands H2pzda (pzda= pyrazine‐2, 3 …

The coordination of rare-earth metal ions (Ln3+) to polyoxometalates (POM) is regarded as
a way of modifying and controlling their properties, such as single-molecular magnetism or …