Expanding Linker Dimensionality in Metal‐organic Frameworks for sub‐Ångstrom Pore Control for Separation Applications

LK Macreadie, KB Idrees, CS Smoljan… - Angewandte …, 2023 - Wiley Online Library
Metal‐organic frameworks (MOFs) are a class of porous materials with high surface areas,
which are acquiring rapid attention on an exponential basis. A significant characteristic of …

Effective approaches to boost Xe/Kr separation in Metal-Organic Frameworks: A review

JF Kurisingal, DW Kim, CS Hong - Coordination Chemistry Reviews, 2024 - Elsevier
Abstract Xenon (Xe) and krypton (Kr) separation is of great interest and plays an essential
role in the industry. However, the identical properties and ultra-low concentrations of Xe and …

Robust carborane-based metal–organic frameworks for hexane separation

KB Idrees, KO Kirlikovali, C Setter, H **e… - Journal of the …, 2023 - ACS Publications
Hexane isomers play a vital role as feedstocks and fuel additives in the petrochemical
industry. However, their similar physical and chemical properties lead to significant …

Six‐Membered Ring Directed Assembly of a Zirconium Zeolitic Metal–Organic Framework for Efficient Separation of Hexane Isomers

L Gan, B Sun, C Xue, Z Fang, Z **ao… - Angewandte …, 2024 - Wiley Online Library
The synthesis of zirconium MOFs with zeolite net is quite challenging due to the high
connectivity of Zr6 clusters, which is far from tetrahedral connection, a requisite for zeolite …

Aperture Fine‐Tuning in Cage‐Like Metal–Organic Frameworks via Molecular Valve Strategy for Efficient Hexane Isomer Separation

R Chen, F Zheng, J Li, Y Liu, F Zhou, H Sun… - Small …, 2024 - Wiley Online Library
Cage‐like metal–organic frameworks (MOFs) are promising for hexane isomer separation,
but their aperture sizes are difficult to control precisely. Herein, a molecular valve strategy is …

Crystallographic and Compositional Dependence of Thermodynamic Stability of [Co (II), Cu (II), and Zn (II)] in 2-Methylimidazole-Containing Zeolitic Imidazolate …

GJ Leonel, CB Lennox, JM Marrett… - Chemistry of …, 2023 - ACS Publications
We report the first systematic study experimentally investigating the effect of changes to the
divalent metal node on the thermodynamic stability of three-dimensional (3D) and two …

Flexibility-frustrated porosity for enhanced selective CO2 adsorption in an ultramicroporous metal-organic framework

X Chen, D Menon, X Wang, M He, MRA Kiapi, M Asgari… - Chem, 2025 - cell.com
Selective CO 2 capture from industry is crucial for reducing emissions from fossil fuel
combustion. Flexible metal-organic frameworks (MOFs) have shown promise for CO 2 …

Near-perfect separation of alicyclic ketones and alicyclic alcohols by nonporous adaptive crystals of perethylated pillar [5] arene and pillar [6] arene

J Chen, S Wu, Y Wang, J Zhou - Chinese Chemical Letters, 2025 - Elsevier
The separation of alicyclic ketones and alicyclic alcohols is one of the challenges in the field
of petrochemical industry. However, traditional separation methods suffer from excessive …

Leveraging Adsorption Kinetics and Thermodynamics in a Channel-Pore Interconnected Metal–Organic Framework for Stepwise Splitting Hexanes

XJ **e, ZH Zhang, QY Cao, MY Zhou, H Zeng… - CCS …, 2024 - chinesechemsoc.org
Dibranched hexane isomers, particularly 2, 3-dimethylbutane (23DMB), are of great
significance in upgrading gasoline to high octane numbers. Yet, the separation of 23DMB …

[HTML][HTML] Synthesis and application of iron based metal organic framework for efficient adsorption of azo dyes from textile industry samples

K Goswami, M Ulaganambi, LK Sukumaran… - Advances in Sample …, 2023 - Elsevier
In this work, we have synthesized an iron based metal organic framework for removal of azo-
dyes from textile industry wastewaters. The metal organic framework is comprised of two …