Expanding Linker Dimensionality in Metal‐organic Frameworks for sub‐Ångstrom Pore Control for Separation Applications
Metal‐organic frameworks (MOFs) are a class of porous materials with high surface areas,
which are acquiring rapid attention on an exponential basis. A significant characteristic of …
which are acquiring rapid attention on an exponential basis. A significant characteristic of …
Effective approaches to boost Xe/Kr separation in Metal-Organic Frameworks: A review
Abstract Xenon (Xe) and krypton (Kr) separation is of great interest and plays an essential
role in the industry. However, the identical properties and ultra-low concentrations of Xe and …
role in the industry. However, the identical properties and ultra-low concentrations of Xe and …
Robust carborane-based metal–organic frameworks for hexane separation
Hexane isomers play a vital role as feedstocks and fuel additives in the petrochemical
industry. However, their similar physical and chemical properties lead to significant …
industry. However, their similar physical and chemical properties lead to significant …
Six‐Membered Ring Directed Assembly of a Zirconium Zeolitic Metal–Organic Framework for Efficient Separation of Hexane Isomers
L Gan, B Sun, C Xue, Z Fang, Z **ao… - Angewandte …, 2024 - Wiley Online Library
The synthesis of zirconium MOFs with zeolite net is quite challenging due to the high
connectivity of Zr6 clusters, which is far from tetrahedral connection, a requisite for zeolite …
connectivity of Zr6 clusters, which is far from tetrahedral connection, a requisite for zeolite …
Aperture Fine‐Tuning in Cage‐Like Metal–Organic Frameworks via Molecular Valve Strategy for Efficient Hexane Isomer Separation
Cage‐like metal–organic frameworks (MOFs) are promising for hexane isomer separation,
but their aperture sizes are difficult to control precisely. Herein, a molecular valve strategy is …
but their aperture sizes are difficult to control precisely. Herein, a molecular valve strategy is …
Crystallographic and Compositional Dependence of Thermodynamic Stability of [Co (II), Cu (II), and Zn (II)] in 2-Methylimidazole-Containing Zeolitic Imidazolate …
We report the first systematic study experimentally investigating the effect of changes to the
divalent metal node on the thermodynamic stability of three-dimensional (3D) and two …
divalent metal node on the thermodynamic stability of three-dimensional (3D) and two …
Flexibility-frustrated porosity for enhanced selective CO2 adsorption in an ultramicroporous metal-organic framework
Selective CO 2 capture from industry is crucial for reducing emissions from fossil fuel
combustion. Flexible metal-organic frameworks (MOFs) have shown promise for CO 2 …
combustion. Flexible metal-organic frameworks (MOFs) have shown promise for CO 2 …
Near-perfect separation of alicyclic ketones and alicyclic alcohols by nonporous adaptive crystals of perethylated pillar [5] arene and pillar [6] arene
J Chen, S Wu, Y Wang, J Zhou - Chinese Chemical Letters, 2025 - Elsevier
The separation of alicyclic ketones and alicyclic alcohols is one of the challenges in the field
of petrochemical industry. However, traditional separation methods suffer from excessive …
of petrochemical industry. However, traditional separation methods suffer from excessive …
Leveraging Adsorption Kinetics and Thermodynamics in a Channel-Pore Interconnected Metal–Organic Framework for Stepwise Splitting Hexanes
XJ **e, ZH Zhang, QY Cao, MY Zhou, H Zeng… - CCS …, 2024 - chinesechemsoc.org
Dibranched hexane isomers, particularly 2, 3-dimethylbutane (23DMB), are of great
significance in upgrading gasoline to high octane numbers. Yet, the separation of 23DMB …
significance in upgrading gasoline to high octane numbers. Yet, the separation of 23DMB …
[HTML][HTML] Synthesis and application of iron based metal organic framework for efficient adsorption of azo dyes from textile industry samples
K Goswami, M Ulaganambi, LK Sukumaran… - Advances in Sample …, 2023 - Elsevier
In this work, we have synthesized an iron based metal organic framework for removal of azo-
dyes from textile industry wastewaters. The metal organic framework is comprised of two …
dyes from textile industry wastewaters. The metal organic framework is comprised of two …