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Nitrenium ions: structure and reactivity
Data on the structure and reactivity of different nitrenium ions are generalised and described
systematically. Various reaction pathways of these reactive intermediates resulted from their …
systematically. Various reaction pathways of these reactive intermediates resulted from their …
How do redox groups behave around a rigid molecular platform? Hexa (ferrocenylethynyl) benzenes and their “electrostatic” redox chemistry
A new family of hexakis (ferrocenylethynyl) benzenes was synthesized by Negishi coupling
from ethynylferrocenes and C6Br6 and can be reversibly oxidized to stable hexaferrocenium …
from ethynylferrocenes and C6Br6 and can be reversibly oxidized to stable hexaferrocenium …
Generation and direct observation of a triplet arylnitrenium ion
Nitrenium ions are important reactive intermediates in both chemistry and biology. Although
singlet nitrenium ions are well-characterized by direct methods, the triplet states of nitrenium …
singlet nitrenium ions are well-characterized by direct methods, the triplet states of nitrenium …
An Unprecedented Formal [5 + 2] Cycloaddition of Nitrones with o-Carboryne via Tandem [3 + 2] Cycloaddition/Oxygen Migration/Aromatization Sequence
Heterocyclic skeletons are widespread among natural products as well as bioactive
molecules. Cycloaddition reaction has created new opportunities to access heterocycles of …
molecules. Cycloaddition reaction has created new opportunities to access heterocycles of …
Long-Cycling Lithium–Sulfur Batteries Enabled by Reactivating Inactive Lithium
High-energy-density lithium–sulfur (Li–S) batteries are attractive but hindered by short cycle
life. The formation and accumulation of inactive Li deteriorate the battery stability. Herein, a …
life. The formation and accumulation of inactive Li deteriorate the battery stability. Herein, a …
Optical and EPR detection of a triplet ground state phenyl nitrenium ion
Nitrenium ions are important reactive intermediates participating in the synthetic chemistry
and biological processes. Little is known about triplet phenyl nitrenium ions regarding their …
and biological processes. Little is known about triplet phenyl nitrenium ions regarding their …
Meta-Substituted Asymmetric Azobenzenes: Insights into Structure–Property Relationship
This article presents a comprehensive investigation into the functionalization of
methoxyphenylazobenzene using electron-directing groups located at the meta position …
methoxyphenylazobenzene using electron-directing groups located at the meta position …
Tuning the sensitization pathway T1→ 5DJ in Eu-based MOF through modification of the antenna ligand. A theoretical approach via multiconfigurational quantum …
The current study demonstrates the possibility of improving the efficiency of Eu 3+
sensitization in an Eu-based MOF, labelled as EuL-R, by modifying the antenna ligand. The …
sensitization in an Eu-based MOF, labelled as EuL-R, by modifying the antenna ligand. The …
Structurally simple benzyl-type photolabile protecting groups for direct release of alcohols and carboxylic acids
Structurally Simple Benzyl-Type Photolabile Protecting Groups for Direct Release of Alcohols
and Carboxylic Acids | Organic Letters ACS ACS Publications C&EN CAS Find my institution Log …
and Carboxylic Acids | Organic Letters ACS ACS Publications C&EN CAS Find my institution Log …
Geometry and energy of substituted phenyl cations
The geometry and the energy of a number of substituted phenyl cations have been
calculated for both spin states at the UB3LYP/6-31G (d) level (o-, m-, p-Me, OMe, NH2, CN …
calculated for both spin states at the UB3LYP/6-31G (d) level (o-, m-, p-Me, OMe, NH2, CN …