Quantum mechanical continuum solvation models

J Tomasi, B Mennucci, R Cammi - Chemical reviews, 2005 - ACS Publications
This review on continuum solvation models has been preceded in Chemical Reviews by
others addressing the same subject. They are due to Tomasi and Persico1 (published in …

Computational approaches for organic semiconductors: from chemical and physical understanding to predicting new materials

V Bhat, CP Callaway, C Risko - Chemical Reviews, 2023 - ACS Publications
While a complete understanding of organic semiconductor (OSC) design principles remains
elusive, computational methods─ ranging from techniques based in classical and quantum …

Extensive TD-DFT benchmark: singlet-excited states of organic molecules

D Jacquemin, V Wathelet, EA Perpete… - Journal of Chemical …, 2009 - ACS Publications
Extensive Time-Dependent Density Functional Theory (TD-DFT) calculations have been
carried out in order to obtain a statistically meaningful analysis of the merits of a large …

Calculation of solvent shifts on electronic g-tensors with the conductor-like screening model (COSMO) and its self-consistent generalization to real solvents (direct …

S Sinnecker, A Rajendran, A Klamt… - The Journal of …, 2006 - ACS Publications
The conductor-like screening model (COSMO) was used to investigate the solvent influence
on electronic g-values of organic radicals. The previously studied diphenyl nitric oxide and …

Dye chemistry with time-dependent density functional theory

AD Laurent, C Adamo, D Jacquemin - Physical Chemistry Chemical …, 2014 - pubs.rsc.org
In this perspective, we present an overview of the determination of excited-state properties of
“real-life” dyes, and notably of their optical absorption and emission spectra, performed …

Pyridinium N-Phenolate Betaine Dyes

VG Machado, RI Stock, C Reichardt - Chemical reviews, 2014 - ACS Publications
It is well-known that the solvent can strongly influence the course, rate, and equilibrium
position of many chemical reactions. 1, 2 The position and intensity of the bands in the …

On the performances of the M06 family of density functionals for electronic excitation energies

D Jacquemin, EA Perpete, I Ciofini… - Journal of Chemical …, 2010 - ACS Publications
We assessed the accuracy of the four members of the M06 family of functionals (M06-L,
M06, M06-2X, and M06-HF) for the prediction of electronic excitation energies of main-group …

Excited-state calculations with TD-DFT: from benchmarks to simulations in complex environments

D Jacquemin, B Mennucci, C Adamo - Physical chemistry chemical …, 2011 - pubs.rsc.org
In this perspective, we present an overview of recent progress on Time-Dependent Density
Functional Theory (TD-DFT) with a specific focus on its accuracy and on models able to take …

Optimizing calculations of electronic excitations and relative hyperpolarizabilities of electrooptic chromophores

LE Johnson, LR Dalton… - Accounts of Chemical …, 2014 - ACS Publications
Conspectus Organic glasses containing chromophores with large first hyperpolarizabilities
(β) are promising for compact, high-bandwidth, and energy-efficient electro-optic devices …

Structures and properties of electronically excited chromophores in solution from the polarizable continuum model coupled to the time-dependent density functional …

B Mennucci, C Cappelli, CA Guido… - The Journal of …, 2009 - ACS Publications
This paper provides an overview of recent research activities concerning the quantum-
mechanical description of structures and properties of electronically excited chromophores …