Size-and shape-dependent catalytic performances of oxidation and reduction reactions on nanocatalysts

S Cao, FF Tao, Y Tang, Y Li, J Yu - Chemical Society Reviews, 2016 - pubs.rsc.org
Heterogeneous catalysis is one of the most important chemical processes of various
industries performed on catalyst nanoparticles with different sizes or/and shapes. In the past …

Chemoselective hydrogenation of carbonyl compounds over heterogeneous catalysts

P Mäki-Arvela, J Hájek, T Salmi, DY Murzin - Applied Catalysis A: General, 2005 - Elsevier
Chemoselective hydrogenation of unsaturated aldehydes and ketones over heterogeneous
catalysts is a demanding task. The achieved selectivity levels depend both on the electronic …

Bimetallic monolayer catalyst breaks the activity–selectivity trade-off on metal particle size for efficient chemoselective hydrogenations

Q Guan, C Zhu, Y Lin, EI Vovk, X Zhou, Y Yang, H Yu… - Nature Catalysis, 2021 - nature.com
Particle size governs the geometric and electronic structure of metal nanoparticles (NPs),
sha** their catalytic performance. However, size-dependent entanglement in the …

Highly selective catalysts for the hydrogenation of unsaturated aldehydes: a review

X Lan, T Wang - ACS catalysis, 2020 - ACS Publications
The selective hydrogenation of unsaturated aldehydes (UAL) to saturated aldehydes (SAL)
and unsaturated alcohols (UOL) is an important industrial process for producing fine …

Disentangling the size-dependent geometric and electronic effects of palladium nanocatalysts beyond selectivity

H Wang, XK Gu, X Zheng, H Pan, J Zhu, S Chen… - Science …, 2019 - science.org
The prominent size effect of metal nanoparticles shapes decisively nanocatalysis, but
entanglement of the corresponding geometric and electronic effects prevents exploiting their …

Electrolytic deuteration of unsaturated bonds without using D2

A Kurimoto, RS Sherbo, Y Cao, NWX Loo… - Nature Catalysis, 2020 - nature.com
Site-selective deuteration of C–H bonds increases the lifetime and efficacy of drug
molecules. Although effective methods to form C (sp 2)–D bonds are known, processes for …

Transforming nonselective into chemoselective metal catalysts for the hydrogenation of substituted nitroaromatics

A Corma, P Serna, P Concepción… - Journal of the American …, 2008 - ACS Publications
It is generally accepted that good hydrogenation noble and nonnoble metal catalysts such
as Pt, Ru, or Ni are not chemoselective for hydrogenation of nitro groups in substituted …

An overview of dehydration, aldol-condensation and hydrogenation processes for production of liquid alkanes from biomass-derived carbohydrates

JN Chheda, JA Dumesic - Catalysis Today, 2007 - Elsevier
We present results for the conversion of carbohydrate feedstocks to liquid alkanes by the
combination of dehydration, aldol-condensation/hydrogenation, and dehydration …

The surface chemistry of metal-based hydrogenation catalysis

F Zaera - ACS Catalysis, 2017 - ACS Publications
The promotion of hydrogenation reactions by transition-metal-based heterogeneous
catalysts was established many decades ago but is still quite common in the chemical …

Selective hydrogenation of ά, β-unsaturated aldehydes and other C= O and C= C bonds containing compounds

P Claus - Topics in Catalysis, 1998 - Springer
Advances in develo** new heterogeneous catalysts which hydrogenate preferentially the
C= O group of ά, β-unsaturated aldehydes to obtain the desired products, namely …