Beyond charge balance: counter‐cations in polyoxometalate chemistry

A Misra, K Kozma, C Streb… - Angewandte Chemie …, 2020 - Wiley Online Library
Polyoxometalates (POMs) are molecular metal‐oxide anions applied in energy conversion
and storage, manipulation of biomolecules, catalysis, as well as materials design and …

Engineering polyoxometalates with emergent properties

HN Miras, J Yan, DL Long, L Cronin - Chemical Society Reviews, 2012 - pubs.rsc.org
Polyoxometalates are clusters of metal-oxide units, comprising a large diversity of nanoscale
structures, and have many common building blocks; in fact polyoxometalate clusters are …

Surface-exposed silver nanoclusters inside molecular metal oxide cavities

K Yonesato, D Yanai, S Yamazoe, D Yokogawa… - Nature Chemistry, 2023 - nature.com
The surfaces of metal nanoclusters, including their interface with metal oxides, exhibit a high
reactivity that is attractive for practical purposes. This high reactivity, however, has also …

Multicomponent Self‐Assembly of a Giant Heterometallic Polyoxotungstate Supercluster with Antitumor Activity

JC Liu, JF Wang, Q Han, P Shangguan… - Angewandte …, 2021 - Wiley Online Library
The hierarchical aggregation of molecular nanostructures from multiple components is a
grand synthetic challenge, which requires highly selective linkage control. We demonstrate …

Polyoxometalate water oxidation catalysts and the production of green fuel

H Lv, YV Geletii, C Zhao, JW Vickers, G Zhu… - Chemical Society …, 2012 - pubs.rsc.org
In the last five years and currently, research on solar fuels has been intense and no sub-
area in this field has been more active than the development of water oxidation catalysts …

Polyoxometalate functionalized architectures

JX Liu, XB Zhang, YL Li, SL Huang, GY Yang - Coordination Chemistry …, 2020 - Elsevier
Polyoxometalates (POMs) are interesting clusters that attracted great attention due to their
remarkable structures and intriguing applications. The incorporation of POMs into crystalline …

Polyoxometalate based open-frameworks (POM-OFs)

HN Miras, L Vilà-Nadal, L Cronin - Chemical Society Reviews, 2014 - pubs.rsc.org
Polyoxometalate-based open frameworks (POM-OFs) are extended architectures
incorporating metal-oxide cluster units and comprise an emergent family of materials with a …

Polyoxometalate-based metal organic frameworks (POMOFs): structural trends, energetics, and high electrocatalytic efficiency for hydrogen evolution reaction

B Nohra, H El Moll, LM Rodriguez Albelo… - Journal of the …, 2011 - ACS Publications
The grafting of the triangular 1, 3, 5-benzene tricarboxylate linkers (denoted trim) on
tetrahedral ε-Keggin polyoxometalates (POMs) capped by Zn (II) ions, formed in situ under …

Controllable Transition Metal-Directed Assembly of [Mo2O2S2]2+ Building Blocks into Smart Molecular Humidity-Responsive Actuators

B Li, X Duan, D Cheng, X Chen, Z Gao… - Journal of the …, 2022 - ACS Publications
Smart molecular actuators have become a cutting-edge theme due to their ability to convert
chemical energy into mechanical energy under external stimulations. However, realizing …

Design and synthesis of polyoxometalate-framework materials from cluster precursors

L Vilà-Nadal, L Cronin - Nature Reviews Materials, 2017 - nature.com
Inorganic oxide materials are used in semiconductor electronics, ion exchange, catalysis,
coatings, gas sensors and as separation materials. Although their synthesis is well …