Sublimable spin‐crossover complexes: From spin‐state switching to molecular devices

KS Kumar, M Ruben - Angewandte Chemie International …, 2021 - Wiley Online Library
Spin‐crossover (SCO) active transition metal complexes are an important class of
switchable molecular materials due to their bistable spin‐state switching characteristics at or …

Spin‐Crossover Molecules on Surfaces: From Isolated Molecules to Ultrathin Films

L Kipgen, M Bernien, F Tuczek, W Kuch - Advanced Materials, 2021 - Wiley Online Library
Molecular spintronics seeks to use single or few molecules as functional building blocks for
spintronic applications, directly relying on molecular properties or properties of interfaces …

Spin‐Crossover Grafted Monolayer of a Co (II) Terpyridine Derivative Functionalized with Carboxylic Acid Groups

V García‐López, N Giaconi, L Poggini… - Advanced Functional …, 2023 - Wiley Online Library
The synthesis and characterization of a new Co (II) spin‐crossover (SCO) complex based on
4′‐(4‐carboxyphenyl)− 2, 2′: 6′, 2 ″‐terpyridine ligand are reported. This complex can …

The influence of the substrate on the functionality of spin crossover molecular materials

S Yazdani, J Phillips, TK Ekanayaka, R Cheng… - Molecules, 2023 - mdpi.com
Spin crossover complexes are a route toward designing molecular devices with a facile
readout due to the change in conductance that accompanies the change in spin state …

Spin-crossover complexes in direct contact with surfaces

M Gruber, R Berndt - Magnetochemistry, 2020 - mdpi.com
The transfer of the inherent bistability of spin crossover compounds to surfaces has attracted
considerable interest in recent years. The deposition of the complexes on surfaces allows …

Nonvolatile voltage controlled molecular spin-state switching for memory applications

TK Ekanayaka, G Hao, A Mosey, AS Dale, X Jiang… - Magnetochemistry, 2021 - mdpi.com
Nonvolatile, molecular multiferroic devices have now been demonstrated, but it is worth
giving some consideration to the issue of whether such devices could be a competitive …

Design and processing as ultrathin films of a sublimable Iron (II) spin crossover material exhibiting efficient and fast light-induced spin transition

M Gavara-Edo, FJ Valverde-Muñoz… - Chemistry of …, 2023 - ACS Publications
Materials based on spin crossover (SCO) molecules have centered the attention in
molecular magnetism for more than 40 years as they provide unique examples of …

Asymmetric design of spin-crossover complexes to increase the volatility for surface deposition

M Gakiya-Teruya, X Jiang, D Le, O Ungor… - Journal of the …, 2021 - ACS Publications
A mononuclear complex [Fe (t Bu2qsal) 2] has been obtained by a reaction between an Fe
(II) precursor salt and a tridentate ligand 2, 4-di (tert-butyl)-6-((quinoline-8-ylimino) methyl) …

Spin‐State Modulation in FeII‐Based Hofmann‐Type Coordination Polymers: From Molecules to Materials

B Kumar, A Paul, DJ Mondal, P Paliwal… - The Chemical …, 2022 - Wiley Online Library
Spin crossover complexes that reversibly interconvert between two stable states imitate a
binary state of 0 and 1, delivering a promising possibility to address the data processing …

Sublimable complexes with spin switching: chemical design, processing as thin films and integration in graphene-based devices

M Gavara-Edo, FJ Valverde-Muñoz… - Journal of Materials …, 2023 - pubs.rsc.org
Among the different types of switchable molecular compounds, sublimable Fe (II) SCO
molecules provide a suitable platform to develop smart devices that respond to external …