Gold-catalyzed homogeneous (cyclo) isomerization reactions

M Marín-Luna, O Nieto Faza, C Silva López - Frontiers in Chemistry, 2019 - frontiersin.org
Gold is currently one of the most used metals in organometallic catalysis. The ability of gold
to activate unsaturated groups in different modes, together with its tolerance to a wide range …

Design and synthesis of alanine triazole ligands and application in promotion of hydration, allene synthesis and borrowing hydrogen reactions

Y Yang, A Qin, K Zhao, D Wang… - Advanced Synthesis & …, 2016 - Wiley Online Library
A new type of alanine triazole (ATA) ligand was found to be an efficient partner for the
stabilization of gold (III), thus rendering improved stability and high catalytic activities in …

Where does Au coordinate to N-(2-pyridiyl) benzotriazole: gold-catalyzed chemoselective dehydrogenation and borrowing hydrogen reactions

R Huang, Y Yang, DS Wang, L Zhang… - Organic Chemistry …, 2018 - pubs.rsc.org
Where does Au coordinate to N-(2-pyridiyl) benzotriazole? Here, pyridyltriazole gold (I)
complexes were synthesized, whereby it was revealed that the triazole part coordinated to …

Preparation of Triazole Gold(III) Complex as an Effective Catalyst for the Synthesis of E‐α‐Haloenones

Y Yang, W Hu, X Ye, D Wang… - Advanced Synthesis & …, 2016 - Wiley Online Library
The pyridyltriazole ligand was prepared and applied as a new ligand system for the
coordination towards gold (III) cations. The resulting complex showed excellent stability and …

Regio‐and Site‐selective Molecular Rearrangements by Homogeneous Gold Catalysis

C Praveen - Asian Journal of Organic Chemistry, 2020 - Wiley Online Library
Homogeneous gold catalysis for connection and disconnection of carbon‐carbon (C− C) as
well as carbon‐heteroatom (C− X) bond constitutes an important zone in molecular …

Rapid Access to Oxa‐Bridged Bicyclic Skeletons through Gold‐Catalyzed Tandem Rearrangement Reaction

J Zhang, Z Liao, L Chen, S Zhu - Chemistry–A European …, 2019 - Wiley Online Library
A gold (I)‐catalyzed reaction of enyne‐ethers to rapidly construct oxa‐bridged compounds
via a tandem 1, 2‐acyloxy migration/intramolecular oxonium formation/1, 2‐rearrangement …

Triazole acetyl gold (III) catalyzed Meyer–Schuster rearrangement of propargyl alcohols

Y Yang, Y Shen, X Wang, Y Zhang, D Wang, X Shi - Tetrahedron Letters, 2016 - Elsevier
A new type triazole acetyl gold (III) was prepared and found to be an effective catalyst in
Meyer–Schuster rearrangement of propargyl alcohols. The reactions proceeded well under …

Triazole–gold promoted intermolecular propargyl alcohol addition to alkyne: the reaction cascade toward substituted allenes

S Hosseyni, S Ding, Y Su, NG Akhmedov… - Chemical …, 2016 - pubs.rsc.org
Gold-catalyzed intermolecular propargyl alcohol addition to alkyne was achieved. The
reaction of propargyl alcohol with a typical gold catalyst gave the hydration product almost …

Effect of substituent on the mechanism and chemoselectivity of the gold (I)-catalyzed propargyl ester tandem cyclization

Y Li, AM Kirillov, R Fang, L Yang - Organometallics, 2017 - ACS Publications
This study reports a detailed theoretical analysis of the mechanisms and chemoselectivity for
the formation of benzo [b] fluorenes or benzofulvenes from propargyl esters catalyzed by an …

Au-Catalyzed Hexannulation and Pt-Catalyzed Pentannulation of Propargylic Ester Bearing a 2-Alkynyl-phenyl Substituent: A Comparative DFT Study

A Ghosh, A Basak, K Chakrabarty, S Mondal… - ACS …, 2018 - ACS Publications
The mechanistic pathways of metal-catalyzed pentannulation and hexannulation of aromatic
enediyne were studied quantum mechanically with Pt and Au salts. In agreement with the …