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Gold-catalyzed homogeneous (cyclo) isomerization reactions
Gold is currently one of the most used metals in organometallic catalysis. The ability of gold
to activate unsaturated groups in different modes, together with its tolerance to a wide range …
to activate unsaturated groups in different modes, together with its tolerance to a wide range …
Design and synthesis of alanine triazole ligands and application in promotion of hydration, allene synthesis and borrowing hydrogen reactions
Y Yang, A Qin, K Zhao, D Wang… - Advanced Synthesis & …, 2016 - Wiley Online Library
A new type of alanine triazole (ATA) ligand was found to be an efficient partner for the
stabilization of gold (III), thus rendering improved stability and high catalytic activities in …
stabilization of gold (III), thus rendering improved stability and high catalytic activities in …
Where does Au coordinate to N-(2-pyridiyl) benzotriazole: gold-catalyzed chemoselective dehydrogenation and borrowing hydrogen reactions
R Huang, Y Yang, DS Wang, L Zhang… - Organic Chemistry …, 2018 - pubs.rsc.org
Where does Au coordinate to N-(2-pyridiyl) benzotriazole? Here, pyridyltriazole gold (I)
complexes were synthesized, whereby it was revealed that the triazole part coordinated to …
complexes were synthesized, whereby it was revealed that the triazole part coordinated to …
Preparation of Triazole Gold(III) Complex as an Effective Catalyst for the Synthesis of E‐α‐Haloenones
Y Yang, W Hu, X Ye, D Wang… - Advanced Synthesis & …, 2016 - Wiley Online Library
The pyridyltriazole ligand was prepared and applied as a new ligand system for the
coordination towards gold (III) cations. The resulting complex showed excellent stability and …
coordination towards gold (III) cations. The resulting complex showed excellent stability and …
Regio‐and Site‐selective Molecular Rearrangements by Homogeneous Gold Catalysis
C Praveen - Asian Journal of Organic Chemistry, 2020 - Wiley Online Library
Homogeneous gold catalysis for connection and disconnection of carbon‐carbon (C− C) as
well as carbon‐heteroatom (C− X) bond constitutes an important zone in molecular …
well as carbon‐heteroatom (C− X) bond constitutes an important zone in molecular …
Rapid Access to Oxa‐Bridged Bicyclic Skeletons through Gold‐Catalyzed Tandem Rearrangement Reaction
J Zhang, Z Liao, L Chen, S Zhu - Chemistry–A European …, 2019 - Wiley Online Library
A gold (I)‐catalyzed reaction of enyne‐ethers to rapidly construct oxa‐bridged compounds
via a tandem 1, 2‐acyloxy migration/intramolecular oxonium formation/1, 2‐rearrangement …
via a tandem 1, 2‐acyloxy migration/intramolecular oxonium formation/1, 2‐rearrangement …
Triazole acetyl gold (III) catalyzed Meyer–Schuster rearrangement of propargyl alcohols
Y Yang, Y Shen, X Wang, Y Zhang, D Wang, X Shi - Tetrahedron Letters, 2016 - Elsevier
A new type triazole acetyl gold (III) was prepared and found to be an effective catalyst in
Meyer–Schuster rearrangement of propargyl alcohols. The reactions proceeded well under …
Meyer–Schuster rearrangement of propargyl alcohols. The reactions proceeded well under …
Triazole–gold promoted intermolecular propargyl alcohol addition to alkyne: the reaction cascade toward substituted allenes
Gold-catalyzed intermolecular propargyl alcohol addition to alkyne was achieved. The
reaction of propargyl alcohol with a typical gold catalyst gave the hydration product almost …
reaction of propargyl alcohol with a typical gold catalyst gave the hydration product almost …
Effect of substituent on the mechanism and chemoselectivity of the gold (I)-catalyzed propargyl ester tandem cyclization
Y Li, AM Kirillov, R Fang, L Yang - Organometallics, 2017 - ACS Publications
This study reports a detailed theoretical analysis of the mechanisms and chemoselectivity for
the formation of benzo [b] fluorenes or benzofulvenes from propargyl esters catalyzed by an …
the formation of benzo [b] fluorenes or benzofulvenes from propargyl esters catalyzed by an …
Au-Catalyzed Hexannulation and Pt-Catalyzed Pentannulation of Propargylic Ester Bearing a 2-Alkynyl-phenyl Substituent: A Comparative DFT Study
The mechanistic pathways of metal-catalyzed pentannulation and hexannulation of aromatic
enediyne were studied quantum mechanically with Pt and Au salts. In agreement with the …
enediyne were studied quantum mechanically with Pt and Au salts. In agreement with the …