Iron‐catalyzed C− H amination is emerging as an attractive and sustainable method to
install amine functionalities into organic compounds. Amination of C (sp3)− H bonds is …

The synthesis, characterization, and reactivity of a series of cobalt terminal imido complexes
supported by an N-anchored tripodal tris (carbene) chelate is described, including a Co …

The nuanced role of spin effects remains a critical gap in designing proficient open‐shell
catalysts. This study elucidates an iron‐catalyzed allylic C (sp3)− H silylation/alkyne …

Tuning the spin state of metal carbynes, which have broad applications in organic synthesis
and material science, presents a formidable challenge for modern chemists as the strong …

Transition metal catalyzed alkene double bond transposition usually involves metal hydride
intermediates. Despite significant advances in the design of catalysts that dictate product …

Reaction of the CoI complex [(TIMMNmes) CoI](PF6)(1)(TIMMNmes= tris‐[2‐(3‐mesityl‐
imidazolin‐2‐ylidene)‐methyl] amine) with mesityl azide yields the CoIII imide [(TIMMNmes) …

The presence of redox innocent metal ions has been proposed to modulate the reactivity of
metal ligand multiple bonds; however, insight from structure/function relationships is limited …

Herein, we report the reactions of an Fe (II) imido complex [Ph2B (t BuIm) 2Fe═ NDipp]−(1)
with internal alkynes and isobutyronitrile, affording the Fe amido allenyl complexes [Ph2B (t …

High-spin, late transition metal imido complexes have attracted significant interest due to
their group transfer reactivity and catalytic C–H activation of organic substrates. Reaction of …

As nitrogen analogues of iron‐oxo species, high‐valent iron‐imido species have attracted
great interest in the past decades. FeV‐alkylimido species are generally considered to be …