Engineering precise sequence-defined polymers for advanced functions
Unlike natural macromolecules (eg, nucleic acids and proteins) possessing precisely
defined molar mass, chain sequence, chirality, and topology, synthetic polymers are typically …
defined molar mass, chain sequence, chirality, and topology, synthetic polymers are typically …
Applications of discrete synthetic macromolecules in life and materials science: recent and future trends
In the last decade, the field of sequence‐defined polymers and related ultraprecise,
monodisperse synthetic macromolecules has grown exponentially. In the early stage, mainly …
monodisperse synthetic macromolecules has grown exponentially. In the early stage, mainly …
Digital micelles of encoded polymeric amphiphiles for direct sequence reading and ex vivo label-free quantification
Q Shi, H Yin, R Song, J Xu, J Tan, X Zhou, J Cen… - Nature Chemistry, 2023 - nature.com
Identification and quantification of synthetic polymers in complex biological milieu are crucial
for delivery, sensing and scaffolding functions, but conventional techniques based on …
for delivery, sensing and scaffolding functions, but conventional techniques based on …
Properties and applications of precision oligomer materials; where organic and polymer chemistry join forces
B van Genabeek, BAG Lamers… - Journal of Polymer …, 2021 - Wiley Online Library
Precise oligomeric materials constitute a growing area of research with implications for
various applications as well as fundamental studies. Notably, this field of science which can …
various applications as well as fundamental studies. Notably, this field of science which can …
Crystallization‐Driven Controlled Two‐Dimensional (2D) Assemblies from Chromophore‐Appended Poly (L‐lactide) s: Highly Efficient Energy Transfer on a 2D …
A rational approach towards precision two‐dimensional (2D) assemblies by crystallization‐
driven self‐assembly (CDSA) of poly (L‐lactides)(PLLAs), end‐capped with dipolar dyes like …
driven self‐assembly (CDSA) of poly (L‐lactides)(PLLAs), end‐capped with dipolar dyes like …
Emerging trends in solution self-assembly of block copolymers
Since the foundation of macromolecular science by Staudinger, advances in polymer
chemistry have unveiled enormous avenues for controlling chemical structures at the …
chemistry have unveiled enormous avenues for controlling chemical structures at the …
Controlled Self‐Assembly of Discrete Amphiphilic Oligourethanes with a Cascade Self‐Immolative Motif
Discrete polymers offer an excellent platform for comprehending the interplay between
precise chain structures, distinctive self‐assembly behavior, and functional applications …
precise chain structures, distinctive self‐assembly behavior, and functional applications …
Topologically Precise and Discrete Bottlebrush Polymers: Synthesis, Characterization, and Structure–Property Relationships
As the complexity of polymer structure grows, so do the challenges for develo** an
accurate understanding of their structure–property relationships. Here, the synthesis of …
accurate understanding of their structure–property relationships. Here, the synthesis of …
Precisely encoding geometric features into discrete linear polymer chains for robust structural engineering
Molecular shape is an essential parameter that regulates the self-organization and
recognition process, which has not yet been well appreciated and exploited in block …
recognition process, which has not yet been well appreciated and exploited in block …
Crystallization-driven self-assembly of block copolymers having monodisperse poly (lactic acid) s with defined stereochemical sequences
Y Kwon, KT Kim - Macromolecules, 2021 - ACS Publications
Monodisperse polymers composed of a discrete number of repeating units have attracted
considerable interest as model systems to investigate the behavior of polymers having …
considerable interest as model systems to investigate the behavior of polymers having …