Advances in the Catalytic Asymmetric Synthesis of Atropisomeric Hexatomic N‐Heterobiaryls
DJ Cheng, YD Shao - Advanced Synthesis & Catalysis, 2020 - Wiley Online Library
Axially chiral hexatomic N‐heterobiaryls are among the most important class of structures
with extensive utility in asymmetric catalysis as chiral ligands and organocatalysts, as …
with extensive utility in asymmetric catalysis as chiral ligands and organocatalysts, as …
Organocatalytic Atroposelective Dynamic Kinetic Resolution Involving Ring Manipulations
Q Shi, F Fang, DJ Cheng - Advanced Synthesis & Catalysis, 2024 - Wiley Online Library
Axially chiral architectures exist widely in natural products, biologically relevant molecules,
chiral ligands and catalysts as well as functional materials. Therefore, catalytic asymmetric …
chiral ligands and catalysts as well as functional materials. Therefore, catalytic asymmetric …
Enantiodivergent Kinetic Resolution of 1, 1′‐Biaryl‐2, 2′‐Diols and Amino Alcohols by Dipeptide‐Phosphonium Salt Catalysis Inspired by the Atherton–Todd …
S Fang, JP Tan, J Pan, H Zhang, Y Chen… - Angewandte Chemie …, 2021 - Wiley Online Library
A highly enantiodivergent organocatalytic method is disclosed for the synthesis of
atropisomeric biaryls via kinetic resolution inspired by a dipeptide‐phosphonium salt …
atropisomeric biaryls via kinetic resolution inspired by a dipeptide‐phosphonium salt …
Combined Dynamic Kinetic Resolution and C− H Functionalization for Facile Synthesis of Non‐Biaryl‐Atropisomer‐Type Axially Chiral Organosilanes
Z Li, X Wang, YM Cui, JH Ma, LL Fang… - … A European Journal, 2021 - Wiley Online Library
Although asymmetric C− H functionalization has been available for the synthesis of
structurally diverse molecules, catalytic dynamic kinetic resolution (DKR) approaches to …
structurally diverse molecules, catalytic dynamic kinetic resolution (DKR) approaches to …
Practical and scalable kinetic resolution of BINOLs mediated by a chiral counterion
BA Jones, T Balan, JD Jolliffe, CD Campbell… - Angewandte …, 2019 - Wiley Online Library
BINOLs are valuable and widely used building blocks, chiral ligands, and catalysts that are
effective across a remarkable range of different chemical transformations. Here we …
effective across a remarkable range of different chemical transformations. Here we …
Kinetic and Dynamic Kinetic Resolution by Dual Catalysis
Kinetic resolution is one of the most common methods to access enantiomerically enriched
compounds. In this method, the resolution is based on the existing difference in reaction …
compounds. In this method, the resolution is based on the existing difference in reaction …
Continuous‐Flow Dynamic Kinetic Resolution of Racemic Alcohols by Lipase–Oxovanadium Cocatalysis
K Higashio, S Katsuragi, D Kundu… - European Journal of …, 2020 - Wiley Online Library
A continuous‐flow dynamic kinetic resolution of racemic secondary alcohols was carried out
using a single column reactor packed with a mixture of immobilized lipase and an …
using a single column reactor packed with a mixture of immobilized lipase and an …
In Situ Structural Determination of a Homogeneous Ruthenium Racemization Catalyst and Its Activated Intermediates Using X‐Ray Absorption Spectroscopy
KPJ Gustafson, A Guðmundsson… - … A European Journal, 2020 - Wiley Online Library
The activation process of a known Ru‐catalyst, dicarbonyl (pentaphenylcyclopentadienyl)
ruthenium chloride, has been studied in detail using time resolved in situ X‐ray absorption …
ruthenium chloride, has been studied in detail using time resolved in situ X‐ray absorption …
Enantiodivergent Synthesis of Axially Chiral Biphenyls from σ‐Symmetric 1, 1'‐Biphenyl‐2, 6‐diol Derivatives by Single Lipase‐Catalyzed Acylative and Hydrolytic …
K Kasama, H Aoyama, S Akai - European Journal of Organic …, 2020 - Wiley Online Library
The enzymatic acylative desymmetrization of σ‐symmetric 2'‐halo‐1, 1'‐biphenyl‐2, 6‐diols
was achieved for the first time using commercially available Burkholderia cepacia lipase …
was achieved for the first time using commercially available Burkholderia cepacia lipase …