A review of methods for the calculation of solution free energies and the modelling of systems in solution

RE Skyner, JL McDonagh, CR Groom… - Physical Chemistry …, 2015‏ - pubs.rsc.org
Over the past decade, pharmaceutical companies have seen a decline in the number of
drug candidates successfully passing through clinical trials, though billions are still spent on …

Power functional theory for many-body dynamics

M Schmidt - Reviews of Modern Physics, 2022‏ - APS
The rich and diverse dynamics of particle-based systems ultimately originates from the
coupling of their degrees of freedom via internal interactions. To arrive at a tractable …

Solvation thermodynamics of organic molecules by the molecular integral equation theory: approaching chemical accuracy

EL Ratkova, DS Palmer, MV Fedorov - Chemical reviews, 2015‏ - ACS Publications
The integral equation theory (IET) of molecular liquids has been an active area of academic
research in theoretical and computational physical chemistry for over 40 years because it …

Intermolecular interaction of diamine-diol binary system: A mini-review

L Zhao, J Zhang - Advances in Colloid and Interface Science, 2022‏ - Elsevier
The highly selective chemical reaction of carbon dioxide with organic amines is considered
to a mature technology and a feasible initial path for carbon capture. In order to solve the …

Combining molecular dynamics and machine learning to predict self-solvation free energies and limiting activity coefficients

J Gebhardt, M Kiesel, S Riniker… - Journal of chemical …, 2020‏ - ACS Publications
Computational prediction of limiting activity coefficients is of great relevance for process
design. For highly nonideal mixtures including molecules with directed interactions, methods …

Solvation free-energy pressure corrections in the three dimensional reference interaction site model

V Sergiievskyi, G Jeanmairet, M Levesque… - The Journal of …, 2015‏ - pubs.aip.org
Solvation free energies are efficiently predicted by molecular density functional theory if one
corrects the overpressure introduced by the usual homogeneous reference fluid …

Hydration free energies of molecular ions from theory and simulation

M Misin, MV Fedorov, DS Palmer - The Journal of Physical …, 2016‏ - ACS Publications
We present a theoretical/computational framework for accurate calculation of hydration free
energies of ionized molecular species. The method is based on a molecular theory, 3D …

[HTML][HTML] Communication: Accurate hydration free energies at a wide range of temperatures from 3D-RISM

M Misin, MV Fedorov, DS Palmer - The Journal of Chemical Physics, 2015‏ - pubs.aip.org
We present a new model for computing hydration free energies by 3D reference interaction
site model (3D-RISM) that uses an appropriate initial state of the system (as suggested by …

Thermodynamic mechanism of selective cocrystallization explored by MD simulation and phase diagram analysis

N Wang, X Huang, H Gong, Y Zhou, X Li, F Li… - AIChE …, 2019‏ - Wiley Online Library
The thermodynamic mechanism of selective cocrystallization was investigated by
combination of molecular dynamics (MD) simulations and phase diagram analysis, using …

Tackling solvent effects by coupling electronic and molecular density functional theory

G Jeanmairet, M Levesque… - Journal of Chemical Theory …, 2020‏ - ACS Publications
Solvation effects can have a tremendous influence on chemical reactions. However, precise
quantum chemistry calculations are most often done either in vacuum neglecting the role of …